Distribution of Free Volume and Dielectric Relaxation due to Segmental Motion of Amorphous Chains in Chlorinated Poly(ethylene)
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概要
- 論文の詳細を見る
The temperature dependence of the shape of the loss permittivity versus frequency plot for the dielectric relaxation due to the segmental motion of amorphous chains in chlorinated poly(ethylene) is explained by a simple theory of the distribution of free volume. The assumptions on which the theory is based are; (1) the free volume distribution obeys the Γ-distribution; (2) the relaxation time depends on the free volume fraction according to a Doolittle-type equation, (3) the relaxation behavior of this process is described by the Williams-Watts' equation. It is also shown that this temperature dependence of the shape of the loss-permittivity curve cannot be explained by a theory of distribution of activation energies.
- 社団法人応用物理学会の論文
- 1986-03-20
著者
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Abe Yuji
Advanced Technology R&d Center Mitsubishi Electric Corporation
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Abe Y
Mitsubishi Electric Corp. Hyogo Jpn
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Abe Yoshio
Department Of Materials Science Faculty Of Engineering Kitami Institute Of Technology
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Hideshima T
Hokkaido Univ. Sapporo Jpn
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Kakizaki M
Hokkaido Univ. Sapporo Jpn
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KAKIZAKI Maeko
Department of Applied Physics, Faculty of Engineering, Hokkaido University
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HIDESHIMA Teruo
Department of Applied Physics, Faculty of Engineering, Hokkaido University
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Kakizaki Maeko
Department Of Applied Physics Faculty Of Engineering Hokkaido University
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Hideshima Teruo
Department Of Applied Physics Faculty Of Engineering Hokkaido University
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Abe Yoshio
Department of Materials Science and Engineering, Faculty of Engineering, Kitami Institute of Technology, 165 Koen-cho, Kitami, Hokkaido 090-8507, Japan
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