Palladium-Catalyzed Condensatino of Aryl Halides with Phenylsulfonylsulfonylacetonitrile and Diethyl Cyanomethyl phosphonate

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概要

• 論文の詳細を見る

• The palladium(0)-catalyzed condensation of aryl halides with the sodium salts of phenylsulfonylacetonitrile and diethyl cyanomethylphonate in dimethoxyethane gave the corresponding α-phenylsulfonylareneacetonitriles and diethyl arylcyanomethylphosphonates in good yields.The α-phenylsulfonylareneacetonitriles were easily desulfonylated with zinc to give the areneacetonitriles, and the arylcyanomethylphonates were converted to the alkylideneareneacetonitriles by means of the Horner-Emmons reaction.

• 公益社団法人日本薬学会の論文
• 1990-06-25

著者

• 根東 義則

  Pharmaceutical Institute, Tohoku University

• 坂本 尚夫

  Pharmaceutical Institute, Tohoku University

• 山中 宏

  Pharmaceutical Institute, Tohoku University

• 加藤 栄作

  Pharmaceutical Institute Tohoku University

• 根東 義則

  Graduate School Of Pharmaceutical Sciences Tohoku University

• 坂本 尚夫

  東北大院薬

• 坂本 尚夫

  Pharmaceutical Institute Tohoku University

• 坂本 尚夫

  東北大学大学院薬学研究科

関連論文

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• Studies on Pyrimidine Derivatives. XXX. The Palladium-Catalyzed Cross-Coupling Reaction of Iodopyrimidines with Terminal Olefinic Compounds
• Studies on Quinoline and Isoquinoline Derivatives. II. Coupling Reaction of Haloquinolines and Haloisoquinolines with Monosubstituted Acetylenes in the Presence of Palladium Complex
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