Medicinal Foodstuffs. XVI. Sugar Beet. (3) : Absolute Stereostructures of Betavulgarosides II and IV, Hypoglycemic Saponins Having a Unique Substituent, from the Roots of Beta vulgaris L.
スポンサーリンク
概要
- 論文の詳細を見る
The absolute stereostructures of betavulgaroside II having a dioxolane-type substituent and betavulgaroside IV having an acetal-type substituent, which were isolated from the roots of Beta vulgaris L. (sugar beet, Chenopodiaceae) and exhibited hypoglycemic activity on glucose-loaded rats, were determined by the chemical correlations of betavulgarosides II and IV with a known saponin, momordin I. In these chemical correlations, the α-L-arabinopyranosyl moiety of momordin I was converted to a dioxolane-type substituent of betavulgaroside II or to an acetal-type substituent of betavulgaroside IV. Additionally, the 2'-diastereoisomer of betavulgaroside IV was synthesized from momordin I, and four acetal-type substituent analogues were also synthesized from L- and D-arabinose.
- 公益社団法人日本薬学会の論文
- 1999-12-15
著者
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MATSUDA Hisashi
Kyoto Pharmaceutical University
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YOSHIKAWA Masayuki
Kyoto Pharmaceutical University
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村上 孝之
Taiho Pharmaceutical Co. Ltd.
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Hiwatashi Kazuyuki
秋田県農林水産技術センター総合食品研究所
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MURAKAMI Toshiyuki
Kyoto Pharmaceutical University
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Hirano Kaoru
Faculty Of Pharmaceutical Sciences Kobe Gakuin University
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Yamazaki M
School Of Pharmaceutical Sciences Kinki University
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Hori K
Kao Co. Ltd. Tochigi Jpn
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Hori Kazuyuki
The Central Research Laboratory Hitachi Ltd.
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HIRANO Kazuhiro
Kyoto Pharmaceutical University
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INADZUKI Masahiro
Kyoto Pharmaceutical University
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INADUKI Masahiro
Kyoto Pharmaceutical University
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Kojima Hiroaki
R&d Co. Kobayashi Pharmaceutical Co. Ltd.
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Hata K
Akita Research Institute Of Food And Brewing
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Kojima Hiroaki
Kobayashi Pharmaceutical Co. Ltd. R&d Company
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MATSUDA HISASHI
Kyoto College of Pharmacy
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Murakami Toshiyuki
Kyoto Institute of Technology
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