Medicianal Foodstuffs. XVII. Fenugreek Seed. (3) : Structures of New Furostanol-Type Steroid Saponins, Trigoneosides Xa, Xb, XIb, XIIa, XIIb, and XIIIa, from the Seeds of Egyptian Trigonella foenum-graecum L.
スポンサーリンク
概要
- 論文の詳細を見る
Six new furostanol-type steroid saponins called trigoneosides Xa, Xb, XIb, XIIa, XIIb, and XIIIa were isolated from the seeds of Egyptian Trigonella foenum-graecum L. (Leguminosae) together with six known furostanol-type steroid saponins : trigoneosides Ia, Ib, and Va, glycoside D, trigonelloside C, and compound C. The structures of trigoneosides Xa, Xb, XIb, XIIa, XIIb, and XIIIa were determined on the basis of chemical and physicochemical evidence as 26-O-β-D-glucopyranosyl-(25S)-5α-furostane-2α, 3β, 22ξ, 26-tetraol 3-O-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-5α-furostane-2α, 3β, 22ξ, 26-tetraol 3-O-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-5α-furostane-2α, 3β, 22ξ, 26-tetraol 3-O-β-D-xylopyranosyl(1→4)-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25S)-furost-4-ene-3β, 22ξ, 26-triol 3-O-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-furost-4-ene-3β, 22ξ, 26-triol 3-O-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside, and 26-O-β-D-glucopyranosyl-(25S)-furost-5-ene-3β, 22ξ, 26-triol 3-O-α-L-rhamnopyranosyl(1→2)-[β-D-glucopyranosyl(1→3)-β-D-glucopyranosyl(1→4)]-β-D-glucopyranoside, respectively.
- 公益社団法人日本薬学会の論文
- 2000-07-01
著者
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MATSUDA Hisashi
Kyoto Pharmaceutical University
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YOSHIKAWA Masayuki
Kyoto Pharmaceutical University
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村上 敏之
京都薬科大学生薬学教室
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村上 孝之
Taiho Pharmaceutical Co. Ltd.
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MURAKAMI Toshiyuki
Kyoto Pharmaceutical University
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KISHI Akinobu
Kyoto Pharmaceutical University
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Kishi A
Kyoto Pharmaceutical University
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Murakami Takayuki
Taiho Pharmaceutical Co. Ltd.
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Yamazaki M
School Of Pharmaceutical Sciences Kinki University
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MATSUDA HISASHI
Kyoto College of Pharmacy
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Murakami Toshiyuki
Kyoto Institute of Technology
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