Medicinal Foodstuffs.XXII.^<1)> Structures of Oleanane-Type Triterpene Oligoglycosides, Pisumsaponins I and II, and Kaurane-Type Diterpene Oligoglycosides, Pisumosides A and B, from Green Peas, the Immature Seeds of Pisum sativum L.
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概要
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Two new oleanane-type triterpene oligoglycosides, pisumsaponins I and II, and two new kaurane-type diterpene oligoglycosides, pisumosides A and B, were isolated from the immature seeds(green peas)of Pisum sativum L. together with soyasaponin I, bersimoside I, dehydrosoyasaponin I, and their 6'-methyl esters. The structures of pisumsaponins and pisumosides were determined on the basis of chemical and physicochemical evidence as 22-O-malonylsoyasapogenol B 3-O-α-L-rhamnopyranosyl(1→2)-β-D-galactopyranosyl(1→2)-β-D-glucopyranosiduronic acid(22-O-malonylsoyasaponin I), sandosapogenol 3-O-α-L-rhamnopyranosyl(1→2)-β-D-galactopyranosyl(1→2)-β-D-glucopyranosiduronic acid, 17-O-β-D-glucopyranosyl-6β, 7β, 13β, 17-tetrahydroxy-19-kauranoic acid 19-O-β-D-glucopyranosyl(1→2)-β-D-glucopyranoside, and 6β, 7β, 13β, 17-tetrahydroxy-19-kauranoic acid 19-O-β-D-glucopyranosyl(1→2)-β-D-glucopyranoside, respectively.
- 公益社団法人日本薬学会の論文
- 2001-01-01
著者
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MATSUDA Hisashi
Kyoto Pharmaceutical University
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YOSHIKAWA Masayuki
Kyoto Pharmaceutical University
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村上 敏之
京都薬科大学生薬学教室
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吉川 雅之
Kyoto Pharmaceutical Univ.
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村上 孝之
Taiho Pharmaceutical Co. Ltd.
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MURAKAMI Toshiyuki
Kyoto Pharmaceutical University
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Murakami Takayuki
Taiho Pharmaceutical Co. Ltd.
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Yamazaki M
School Of Pharmaceutical Sciences Kinki University
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KOHNO Kentarou
Kyoto Pharmaceutical University
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MATSUDA HISASHI
Kyoto College of Pharmacy
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Murakami Toshiyuki
Kyoto Institute of Technology
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