Saccharification of Cellulose by Combined Hydrolysis with Acid and Enzyme : Studies on the Re-utilization of Cellulosic Resources (IV).
スポンサーリンク
概要
- 論文の詳細を見る
Acid hydrolysis of cellulose in heterogeneous and homogeneous systems was studied theoretically and experimentally. In the heterogeneous system, solubilization of cellulose was the rate-limiting step. The low yield of glucose was due to decomposition of glucose and cellooligosaccharides produced from cellulose to other materials than sugars during the long exposure to strong acid. In the homogeneous system, cellulose was hydrolyzed at random, and the rate constant of the hydrolysis k_c(hr^<-1>) at 50℃ was expressed by the following equation.k_<c, 50℃>≒9.4×10^<-8> exp (0.28 [HCl]) where [HCl] represents the concentration of hydrochloric acid in the range of 4 to 16(w/w)%. The activation energy for the hydrolysis of cellulose was 27.8 kcal/mol.The thermal stability of cellulase immobilized on Duolite ES-762 exceeded that of free cellulase. The pH optima of immobilized and free cellulases were in the range of 4.0 to 5.0. The Michaelis constant K_m of immobilized cellulase approximated to that of free cellulase.The total amount of cellulose used was converted first into glucose and soluble cellooligosaccharides by acid hydrolysis in the homogeneous system, and then completely into glucose by hydrolysis with the immobilized cellulase.
- 社団法人日本生物工学会の論文
- 1980-12-25
著者
-
Taniguchi Masayuki
Department of Materials Science and Technology, Niigata University
-
Morinaga Tsutomu
Department Of Food Science And Technology Faculty Of Agriculture Kyoto University:(present Address)d
-
TANAKA MITSUO
Department of Food Science and Technology, Faculty of Agriculture, Kyoto University
-
MORITA TAKUO
Department of Food Science and Technology, Faculty of Agriculture, Kyoto University
-
MATSUNO RYUICHI
Department of Food Science and Technology, Faculty of Agriculture, Kyoto University
-
KAMIKUBO TADASHI
Department of Food Science and Technology, Faculty of Agriculture, Kyoto University
-
Taniguchi M
Fac. Engineering Niigata Jpn
-
Taniguchi M
Department Of Material Science And Technology Faculty Of Engineering
-
Taniguchi Masayuki
Department Of Materials Science And Technology Niigata University
-
Tanaka Mitsuo
Department Of Biochemistry And Molecular Biology Nihon University School Of Dentistry At Matsudo
-
Taniguchi Masayuki
Department Of Cardiology Jikei University School Of Medicine Daisan Hospital
-
Matsuno Ryuichi
Deparment Of Food Science And Technology Faculty Of Agriculture Kyoto University
-
Tanaka Mitsuo
Department Biochemistry Faculty Of Science Okayama University Of Science
-
Kamikubo Tadashi
Deparment Of Food Science And Technology Faculty Of Agriculture Kyoto University
関連論文
- Growth-inhibition of hiochi bacteria in namazake (raw sake) by bacteriocins from lactic acid bacteria(BREWING AND FOOD TECHNOLOGY)
- Evaluation of Fungal Pretreatments for Enzymatic Saccharification of Rice Straw
- Effect of steam explosion pretreatment on treatment with Pleurotus ostreatus for the enzymatic hydrolysis of rice straw(ENVIRONMENTAL BIOTECHNOLOGY)
- Effects of Spironolactone During an Angiotensin II Receptor Blocker Treatment on the Left Ventricular Mass Reduction in Hypertensive Patients With Concentric Left Ventricular Hypertrophy
- Additive Effects of Spironolactone to Angiotensin II Receptor Blocker Monotherapy on Aldosterone Breakthrough in Patients with Essential Hypertension
- Effects of Bradykinin on Cardiovascular Remodeling in Renovascular Hypertensive Rats
- Production of Bifidogenic Growth Stimulator by Co-cultivation of Propionibacterium shermanii and Lactobacillus Strain Using Lactose as a Carbon Source
- Production of Extracellular Bifidogenic Growth Stimulator(BGS) from Propionibacterium shermanii Using a Bioreactor System with a Microfiltration Module and an On-line Controller for Lactic Acid Concentration(BIOCHEMICAL ENGINEERING)
- Production of Extracellular Bifidogenic Growth Stimulator by Anaerobic and Aerobic Cultivations of Several Propionibacterial Strains(BIOCHEMICAL ENGINEERING)
- OJ-052 Holter Parameters for Optimal Ventricular Rate Control in Patients with Chronic Atrial Fibrillation(OJ09,ECG/Body Surface Potential Mapping/Holter (A),Oral Presentation (Japanese),The 73rd Annual Scientific Meeting of The Japanese Circulation Socie
- Chronobiological Analysis by Ambulatory Blood Pressure Monitoring of the Hyperbaric and Hypobaric Indexes for Evaluation of the Antihypertensive Effect of Long-Acting Nifedipine
- Continuous Culture of RPMI 8226 Human Cells
- Saccharification of Cellulose by Combined Hydrolysis with Acid and Enzyme : Studies on the Re-utilization of Cellulosic Resources (IV).
- Cellulase Productivity of Eupenicillium javanicum : Studies on the Re-utilization of Cellulosic Resources (V).
- Production of Superoxide Dismutase from Streptococcus lactis Using a Bioreactor with a Microfiltration Module(Microbiology & Fermentation Industry)
- Rapid Production of Pediococcus halophilus Salt-Tolerant Cells by a Cultivation Method Employing Gradual Increases in NaCl Concentration Using a Fermentor with a Microfiltration Module
- Formaldehyde-Limited Cultivation of a Newly Isolated Methylotrophic Bacterium, Methylobacterium sp. MF1 : Enzymatic Analysis Related to C_1 Metabolism(Biochemical Engineering)
- -43-CLINICAL CHARACTERISTICS OF ACUTE MYOCARDIAL INFARCTION IN PATIENTS WITH DIABETES MELLITUS : WITH RESPECT TO THE INCIDENCE OF POWER FAILURE
- Continuous Lactic Acid Production from Raw Starch in a Fermentation System Using a Reversibly Soluble-autoprecipitating Amylase and Immobilized Cells of Lactobacillus casei(Microbiology & Fermentation Industry)
- Induction of Cytosolic Acetyl-Coenzyme A Carboxylase in Pea Leaves by Ultraviolet-B Irradiation
- FE-P8 Establishment of optimal conditions for extracting protein fractions inhibiting arg-gingipain from polished rice(Section IX Food Engineering)
- FE-P6 Growth-inhibitory activity of antimicrobial peptides from rice against oral pathogenic bacteria and clarification of their action mechanism(Section IX Food Engineering)
- OE-195 Effect of Beta-Blocker on Sarcoplasmic Reticulum Ca Handling and Contractility in Ca-Force-Frequency Relationship in Perfused Rat Heart(Cardiac Function, Basic/Clinical 1 (M) : OE24)(Oral Presentation (English))
- The Effect of Angiotensin Receptor Antagonist and Aldosterone Receptor Antagonist against Cardiac Hypertrophy in Renovascular Hypertensive Rat
- Treatment of Nonylphenol with Laccase in a Rotating Reactor(ENVIRONMENTAL BIOTECHNOLOGY)
- Enzymatic Oxidative Polymerization of 4-Chloroguaiacol by Laccase
- Treatment of Model Soils Contaminated with Phenolic Endocrine-Disrupting Chemicals with Laccase from Trametes sp.in a Rotating Reactor
- Evaluation of Pretreatment with Pleurotus ostreatus for Enzymatic Hydrolysis of Rice Straw(ENVIRONMENTAL BIOTECHNOLOGY)
- Production of L-Lactic Acid by Simultaneous Saccharification and Fermentation Using Unsterilized Defatted Rice Bran as a Carbon Source and Nutrient Components
- Production of a Mixture of Antimicrobial Organic Acids from Lactose by Co-Culture of Bifidobacterium longum and Propionibacterium freudenreichii
- Formation of Inclusion Complexes between Cyclodextrins and Aromatic Compounds under pressurized Carbon Dioxide
- Purification of Recombinant α-Amylase with Immuno-Affinity Chromatography Using Monoclonal Antibody
- Synthesis of Aspartame Precursors by Enzymatic Reaction in Supercritical Carbon Dioxide(Food & Nutrition)
- Brewing of Sake from Rice and Rice-Koji Defatted by Supercritical Carbon Dioxide Treatment
- Effect of Treatment with Supercritical Carbon Dioxide on Enzymatic Activity(Food & Nutrition)
- Sterilization of Microorganisms with Supercritical Carbon Dioxide(Food & Nutrition)
- Effect of Vitamin B_6 Compounds in Some Microorganisms Producing Vitamin B_6
- Preparation of a Novel Thermo-Responsive Polymer and Its Use as a Carrier for Immobilization of Thermolysin
- Repeated Utilization of β-Glucosidase Immobilized on a Reversibly Soluble-Insoluble Polymer for Hydrolysis of Phloridzin as a Model Reaction Producing a Water-Insoluble Product
- Continuous Production of an Antibiotic Polypeptide (Nisin) by Lactococcus lactis Using a Bioreactor Coupled to a Microfiltration Module
- Hydrolysis of Starchy Materials by Repeated Use of an Amylase Immobilized on a Novel Thermo-Responsive Polymer
- PRODUCTION OF ETHANOL FROM RECLAIMED PAPER USING A COMBINATION OF A REVERSIBLY SOLUBLE- AUTOPRECIPITATING CELLULASE AND FLOCCULATING YEAST CELLS
- PROPERTIES OF AMYLASE IMMOBILIZED ON A NEW REVERSIBLY SOLUBLE-INSOLUBLE POLYMER AND ITS APPLICATION TO REPEATED HYDROLYSIS OF SOLUBLE STARCH
- Continuous Ethanol Production from Raw Starch Using a Reversibly Soluble-Autoprecipitating Amylase and Flocculating Yeast Cells
- Two Cases of Transiently TSBAb-Positive Hypothyroidism Induced by Interferon-Alpha Therapy for Chronic Hepatitis C
- Effects of a Peptide Mixture with a High Fischer's Ratio on Serum and Cerebral Cortex Amino Acid Levels and on Cerebral Cortex Monoamine Levels, Compared with an Amino Acid Mixture with a High Fischer's Ratio
- -0937- THE EFFECT OF HYPOXIA ON Na^+/Ca^+ EXCHANGE IN ISOLATED PERFUSED RAT HEART(PROCEEDINGS OF THE 59th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY)
- A POSSIBLE ROLE OF ATP SENSITIVE POTASSIUM CHANNEL ON CARDIAC FUNCTION DURING ISCHEMIA AND REPERFUSION IN ISOLATED PERFUSED RAT HEART
- EFFECT OF PILSICAINIDE HCL, A CLASS I c ANTI-ARRHYTHMIC AGENT, ON INTRACELLULAR Na^+, pH AND REPERFUSION ARRHYTHMIAS.
- NADPH-dependent Reduction of Ethyl Acetoacetate Coupled with Ethanol Oxidation in Kloeckera magna
- Relationship between Ethanol Consumption Rate and Prochiral Ketone Rerducton Rate in Bakers' Yeast
- Oxidative Resolution with Baker's Yeast for Large-Scale Production of Chiral 1,2-Alkanediols
- NAD(P)H Regeneration Using Ethanol as an Energy Source in Baker's Yeast-Mediated Bioreduction
- Large-Scale Preparation of (S)-Ethyl 3-Hydroxybutanoate with a High Enantiomeric Excess through Baker's Yeast-Mediated Bioreduction
- Baker's Yeast Mediated Bioreduction : Practical Procedure Using EtOH at Energy Source
- Bioreduction of Ketones Mediated by Baker's Yeast with Acetate as Ultimate Reducing Agent(Biological Chemistry)
- Evaluation of Fungal Pretreatments for Enzymatic Saccharification of Rice Straw
- Formation of Biodegradable Polyesters Membranes via Thermally Induced Phase Separation
- Preparation of Defatted Mustard by Extraction with Supercritical Carbon Dioxide(Food & Nutrition)
- Ethanol Production from a Mixture of Glucose and Xylose by a Novel Co-Culture System with Two Fermentors and Two Microfiltration Modules
- Ethanol Production from a Mixture of Glucose and Xylose by Co-Culture of Pichia stipitis and a Respiratory-Deficient Mutant of Saccharomyces cerevisiae
- Purification of Staphylococcal Protein A by Affinity Precipitation Using a Reversibly Soluble-Insoluble Polymer with Human IgG as a Ligand
- Elucidation of the Expression Mechanism of the Synergistic Effect on Hydrolysis of Crystalline Cellulose by Cellulases
- Site-Specific and Asymmetric Hydrolysis of Prochiral 2-Phenyl-1,3-propanediol Diacetate by a Bacterial Esterase from an Isolated Strain
- Continuous Oxidation of Aromatic Aldehyde to Aromatic Carboxylic Acid by Burkholderia cepacia TM1 in a Cell-Holding Reactor
- EFFECTS OF HIGH-AND LOW-DENSITY LIPOPROTEINS ON HEMODYNAMICS IN ISOLATED PERFUSED RAT HEART
- Acid Base Changes in Ischemic Myocardium and Intervention with Hypothermia or Bicarbonate : SYMPOSIUM ON PATHOPHYSIOLOGY IN THE EARLY STAGE OF ACUTE MYOCARDIAL INFARCTION AND ITS TREATMENT : 51th Annual Scientific Session of the Japanese Circulation Socie
- Repeated Batch Conversion of Raw Starch to Ethanol Using Amylase Immobilized on a Reversible Soluble-autoprecipitating Carrier and Flocculating Yeast Cells(Microbiology & Fermentation Industry)
- Kinetic Study on Δ^1-Dehydrogenation of Hydrocortisone by Gel-Entrapped Arthrobacter simplex Cells
- Separation of Alkyl β-D-Glucosides and n-Alcohols by Using a Porous Trimethylolpropane Trimethacrylate Homopolymer Gel
- Synthesis of Peptides Consisting of Essential Amino acids by a Reactor System Using Three Proteinases and an Organic Solvent(Microbiology & Fermentation Industry)
- The structures of eicosapentaenoic acid (EPA) derivatives formed during accelerated stability testing of EPA ethylester
- Alcohol Fermentation Using Lignin-Related Compounds as a Carbon Source
- Functional and Metabolic Properties in Hearts from Aged Spontaneously Hypertensive Rats : SYMPOSIUM ON LONG-TERM MYOCARDIAL CHANGES IN HEART DISEASES : 49th Annual Scientific Session of the Japanese Circulation Society
- Possible roles of Na^+/H^+and CI^-/HCO^-_3 exchangers in the development of Ischemia-reperfusion induced arrhythmias
- EFFECT OF ISCHEMIA ON MYOCARDIAL LIPOPROTEIN LIPASE ACTIVITY IN ISOLATED, PERFUSED RAT HEART : Cardiac Metabolism (I) : IV : 48 Annual Scientific Meeting, Japanese Circulation Society
- Poly(L-Lactic Acid) Microfiltration Membrane Formation via Thermally Induced Phase Separation with Drying
- Site-Specific and Asymmetric Hydrolysis of Prochiral 2-Phenyl-1,3-propanediol Diacetate by a Bacterial Esterase from an Isolated Strain
- MYOCARDIAL PROTECTIVE EFFECTS OF INTRINSIC STORAGE IN DIABETIC HEART
- Temperature Dependence of the Distribution Coefficient of Maltooligosaccharides on Cation-exchange Resin in Na^+ Form
- Continuous Synthesis of a Tripeptide by Successive Condensation and Transesterification Catalyzed by Two Immobilized Proteinases in Organic Solvent(Microbiology & Fermentation Industry)
- Retarded Oxidation of Liquid Lipids Entrapped in Matrixes of Saccharides or Proteins
- Large-Scale Preparation of (R)-1,2-Propanediol through Baker's Yeast-Mediated Bioreduction
- Isolation and Characterization of cDNAs That Encode Eleven Small GTP-Binding Proteins from Pisum sativum
- Purification and Properties of Cellulases from Eupencillium javanicum : Studies on the Re-utilization of Cellulosic Resources(VII)
- Methods for Estimating the Parameters of Nonlinear Adsorption Isotherms of Langmuir and Freundlich Types from a Response Curve of Pulse Input of an Adsorbate
- Production of Homochiral 1-Phenylethanol through Enantioselective Oxidation of Its Racemate with Whole Cells of the Yeast Hansenula capsulata IFO 0974
- Model for Estimation of the Stability of Emulsions in a Cream Layer
- Separation of Peptide Groups with Definite Characteristics from Enzymatic Protein Hydrolysate(Food & Nutrition)
- Effect of Culture Conditions on Cellulase Production by Pellicularia filamentosa : Studies on the Re-utilization of Cellulosic Resources (IV).
- Some Factors Affecting Cellulose Degradation with Pellicularia filamentosa Cellulases : Studies on the Re-utilization of Cellulosic Resources (II)
- Production of Vitamin B_ by Methanol-utilizing Bacteria, Pseudomonas AM-1 and Microcyclus eburneus
- Purification and Properties of Cellulases from Pellicularia filamentosa : Studies on the Re-utilization of Cellulosic Resources(I)
- Thermogravimetric Analysis of Cyclodextrin-Fatty Acid Complex Formation and Its Use for Predicting Suppressed Autoxidation of Fatty Acids
- Effect of Eluent Composition on the Distribution Coefficient of Saccharides on to a Cation-exchange Resin in Sodium-ion Form
- Properties of Agents that Effectively Entrap Liquid Lipids
- ATP Regeneration with Enzymes of the Alcohol Fermentation Pathway and Kinases of Yeast and Its Computer Simulation
- Stimulation of in Vitro RNA Synthesis by DNA-Loosely Bound Proteins Treated with Gibberellin A_3
- Increase of RNA Polymerase Activity in Pea Buds Treated with Gibberellic Acid A_3
- Kefiran Production by Lactobacillus kefiranofaciens under the Culture Conditions Established by Mimicking the Existence and Activities of Yeast in Kefir Grains