Formation of Biodegradable Polyesters Membranes via Thermally Induced Phase Separation

概要

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Microfiltration membranes that can be composted after service were developed from biodegradable polyesters, poly(L-lactic acid) (PLLA) and poly(ε-caprolactone) (PCL). The membranes were formed via the thermally induced phase separation method. A 10 wt% PLLA solution in a mixed diluent of 1,4-dioxane and water (87:13 by weight) was prepared in a flat mold and quenched from 52°C (4°C above cloud point temperature) to 0°C. After diluent extraction, the membrane separated yeast cells (6 μm) from their suspensions. A PCL membrane formed by the same method did not reject yeast cells. PCL membranes formed by quenching a 16 wt% PCL solution to 0°C and quenching a 10 wt% PCL solution to –196°C did separate yeast cells from their suspensions. The permeation flux was much higher in the filtration of 1 kg·m–3 yeast cell suspension with the PLLA and PCL membranes formed by quenching a 10 wt% PLLA or PCL solution to –196°C than in the filtration with the PLLA membrane formed by quenching a 10 wt% PLLA solution to 0°C. The higher flux would be due to the lower resistance of the membranes formed by liquid nitrogen quenching (–196°C) and the mode of depth filtration. Porous biodegradable microfiltration membranes prepared from these polymers have the potential to serve as disposable filters in food and biochemical industries.
社団法人化学工学会の論文
2006-02-01