Constituents of Holothuroidea, 16. : Determination of Absolute Configuration of the Branched Methyl Group in Ante-iso Type Side Chain Moiety on Long Chain Base of Glucocerebroside from the Sea Cucumber Holothuria leucospilota

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概要

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• The absolute configuration of the branched methyl group in ante-iso type side chain moiety on the long chain base of glucocerebroside, HLC-2-A, which was isolated from the sea cucumber Holothuria leucospilota was determined. Oxidation of the glucocerebroside with ozone afforded C_<13>-fragment including the ante-iso moiety. The optically active C_<13>-fragment was synthesized asymmetrically by using the Wittig reaction from chiral synton for comparison with the natural fragment.

• 公益社団法人日本薬学会の論文
• 2005-10-01

著者

• INAGAKI MASANORI

  Faculty of Pharmaceutical Sciences, Kyushu University

• HIGUCHI RYUICHI

  Faculty of Pharmaceutical Sciences, Kyushu University

• HIGUCHI Ryuichi

  Graduate School of Pharmaceutical Sciences, Kyushu University

• TANAKA Masakazu

  Faculty of Bioscience, Nagahama Institute of Bio-Science and Technology

• YAMADA Koji

  Faculty of Engineering, Saitama University

• INAGAKI Masanori

  Graduate School of Pharmaceutical Sciences, Kyushu University

• Higuchi Ryuichi

  Graduate School Of Pharmaceutical Sciences Kyushu Univ.

• Higuchi Ryuichi

  Faculty Of Pharmaceutical Sciences Kyushu University

• Tanaka Masakazu

  Graduate School Of Pharmaceutical Sciences Kyushu Univ.

• Yamada K

  Graduate School Of Pharmaceutical Sciences Kyushu University

• ONAKA Hiroyuki

  Faculty of Pharmaceutical Sciences, Kyushu University

• Yamada Katsuya

  Graduate School Of Pharmaceutical Sciences Nagoya City University

• Onaka Hiroyuki

  Faculty Of Pharmaceutical Sciences Kyushu University

• Inagaki Masanori

  Faculty Of Pharmaceutical Sciences Kyushu University

• Yamada Kenji

  Tokyo University Of Pharmacy And Life Sciences School Of Pharmacy

• Ito Masaki

  The First Department Of Internal Medicine Mie University School Of Medicine

• Inagaki M

  Graduate School Of Pharmaceutical Sciences Chiba University

• Yamada Koji

  Faculty Of Engineering Saitama University

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