Growth of Epitaxial {100}-Oriented KNbO₃--NaNbO₃ Solid Solution Films on (100)_\text{cSrRuO₃$\varparallel$(100)SrTiO₃ by Hydrothermal Method and Their Characterization

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概要

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• Films of solid solution in KNbO₃--NaNbO₃ (KNN) were deposited at 240 °C on (100)_\text{cSrRuO₃$\varparallel$(100)SrTiO₃ substrates by the hydrothermal method. (K_xNa_1-x)NbO₃ films with $x = 0{\mbox{--}}1.0$ were synthesized by changing the fraction of KOH in a solution of KOH and NaOH. The $x$ in (K_xNa_1-x)NbO₃ continuously changed with the volume fraction of KOH, while the deposition amount strongly depended on $x$. Epitaxial films with {100} orientation were obtained in the entire composition range and their out-of-plane lattice spacing changed with $x$. All the films showed ferroelectricity and their remanent polarization became larger than what above $x = 0.58$.

• 2011-09-25

著者

• Yasui Shintaro

  Department of Innovative and Engineered Materials, Tokyo Institute of Technology

• Funakubo Hiroshi

  Department Of Innovative And Engineered Materials

• Ishikawa Mutsuo

  Department Of Laboratory Medicine Shinshu University Hospital

• Kurosawa Minoru

  Department Of Advanced Applied Electronics Tokyo Institute Of Technology

• Shiraishi Takahisa

  Department Of Diagnostic Radiology Tohoku University

• Uchida Hiroshi

  Department Of Anesthesia Tottori Prefectural Central Hospital

• Kurosawa Minoru

  Department of Information Processing, Tokyo Institute of Technology, Yokohama 226-8502, Japan

• Hasegawa Tomohito

  Department of Information Processing, Tokyo Institute of Technology, Yokohama 226-8502, Japan

• Einishi Hiro

  Department of Innovative and Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8502, Japan

• Sakashita Yukio

  Frontier Core-Technology Laboratories, Fujifilm Corporation, Kaisei, Kanagawa 258-8577, Japan

• Ishikawa Mutsuo

  Department of Innovative and Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8502, Japan

• Ishikawa Mutsuo

  Department of Advanced Applied Electronics, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Yokohama 226-8503, Japan

• Yasui Shintaro

  Department of Chemistry, Sophia University, 7-1 Kioi-cho, Chiyoda-ku, Tokyo 102-8554, Japan

• Funakubo Hiroshi

  Department of Innovative and Engineered Material, Tokyo Institute of Technology, Yokohama 226-8503, Japan

• Shiraishi Takahisa

  Department of Innovative and Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8502, Japan

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