Kinetic Analysis of Temperature-Programmed Autoxidation of Ethyl Eicosapentaenoate and Ethyl Docosahexaenoate
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概要
- 論文の詳細を見る
On the basis of an autocatalytic and a first order reaction kinetics, a nonisothermal oxidation reaction model was developed for n-3 polyunsaturated fatty acid (PUFA) under temperature-programmed linear heating conditions. With this model, the activation energy of oxidative reaction can easily be obtained with at least three linear heating conditions. The temperature-programmed oxidation experiments of ethyl eicosapentaenoate and ethyl docosahexaenoate were done under linear heating conditions of 4 to 12 K/h. The activation energies and the frequency factors obtained were in good agreement with those by the isothermal oxidation experiments reported previously.
- 社団法人日本農芸化学会の論文
- 1999-08-23
著者
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吉井 英文
鳥取大学大学院工学研究科 化学・生物応用工学専攻
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Kobayashi H
National Food Research Institute
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Kobayashi H
National Food Res. Inst. Ibaraki Jpn
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Linko P
Department Of Chemical Technology Helsinki University Of Technology
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Linko Yu-yen
Department Of Chemical Technology Helsinki University Of Technology
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Itoh Tomoyuki
Department Of Biological Mechanisms And Functions Graduate School Of Bioagricultural Sciences Nagoya
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Kiuchi Hiroshi
Research Development Section Kibun Food Chemifa Co. Ltd.
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Hayashi K
National Food Research Institute Ministry Of Agriculture Forestry And Fisheries
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Furuta Takeshi
Tottori University
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YOSHII Hidefumi
Department of Biotechnology, Tottori University
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FURUTA Takeshi
Department of Biotechnology, Tottori University
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LINKO Pekka
Department of Chemical Technology, Helsinki University of Technology
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MISAWA Yoshihisa
Harima Chemicals Inc.
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HATA Noriaki
Harima Chemicals Inc.
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ITOH Takatoki
Department of Biotechnology, Tottori University
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KOBAYASHI Hideaki
R & D Div., Q.P. Corporation
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Yoshii H
Tottori University
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Yoshii H
Tottori Univ. Tottori Jpn
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Yoshii H
Toyama National Coll. Technol. Toyama Jpn
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Yoshii Hidefumi
Department Of Biochemical Engineering Toyama National College Of Technology
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Itoh T
Laboratory Of Animal Food Science College Of Bioresource Science Nihon University
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Hata N
Harima Chemicals Inc.
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Furuta T
Tottori University
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Furuta Takeshi
Department Of Biotechnology Faculty Of Engineering Tottori University
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Itoh T
Faculty Of Agriculture Iwate University
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Itoh T
Hiroshima Univ. Higashi-hiroshima Jpn
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Linko Pekka
Department Of Chemical Technology Helsinki University Of Technology
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Yoshii Hidefumi
Department Of Applied Biological Science Kagawa University
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