Site Occupancy Analysis on the Enhancement in Dy-Substituted Pb(Zr,Ti)O3 Film
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概要
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The effect of site selectivity on the ferroelectric polarization property was investigated in Dy-substituted Pb(Zr0.4Ti0.6)O3 films prepared on (111)Pt/Ti/SiO2/(100)Si substrates by a chemical solution method. Dy ions were introduced, assuming Pb or Zr and Ti site substitutions in Pb(Zr0.40Ti0.60)O3 with $x$ ranging from 0 to 0.06. Site occupation was determined by Raman spectroscopy. Dy ions selectively replaced the assumed sites at a low $x$ value; however, these ions interdiffused to opposite sites at a high $x$ value. Remnant polarization was enhanced when Dy ions selectivity substituted the Zr and Ti sites at a low $x$ value, while it was contrarily degraded by Pb site substitution. These results provide useful guidelines for ferroelectric property improvement by ion substitution in Pb(Zr0.4Ti0.6)O3.
- 2006-09-30
著者
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Osada Minoru
Advanced Materials Laboratory National Institute For Materials Science
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Funakubo Hiroshi
Department Of Innovative And Engineered Materials
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Nakaki Hiroshi
Department Of Chemistry Sophia University
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Katoda Takashi
Department Of Electronic And Photonic Systems Engineering Kochi University Of Technology
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Koda Seiichiro
Department Of Chemical Engineering Facutly Of Engineering The University Of Tokyo
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Uchida Hiroshi
Department Of Anesthesia Tottori Prefectural Central Hospital
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Osada Minoru
Advanced Materials Laboratory, National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan
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Uchida Hiroshi
Department of Chemistry, Sophia University, Chiyoda-ku, Tokyo 102-8554, Japan
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Funakubo Hiroshi
Department of Innovative and Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8503, Japan
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Nishida Ken
Research Institution of Kochi University of Technology, Kochi 782-8502, Japan
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Nakaki Hiroshi
Department of Innovative and Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8503, Japan
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Funakubo Hiroshi
Department of Innovative and Engineered Material, Tokyo Institute of Technology, Yokohama 226-8503, Japan
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Katoda Takashi
Department of Electronic and Photonic System Engineering, Kochi University of Technology, 185 Tosayamada-cho, Kami, Kochi 782-8502, Japan
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Koda Seiichiro
Department of Chemistry, Sophia University, Chiyoda-ku, Tokyo 102-8554, Japan
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