Studies on Diazepines. VI. Photolysis of 1H-1,2-Diazepine and Azepine Epidioxides
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概要
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The photolysis of 1H-1,2-diazepine 4,7-epidioxides (1) with a low pressure mercury lamp resulted in the formation of 5-ethoxy-1,3,4-oxadiazoles (3), azoxy compounds (4), and diene compounds (5). A reasonable mechanism for the formation of the products may involve initial isomerization to the 1,2,3-oxadiazoles (8), followed by decomposition and isomerization. However, the azepine 2,5-epidioxide (2) gave only the diene compound (6) in a low yield and did not give any other characterized products.
- 社団法人日本薬学会の論文
- 1978-07-25
著者
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井下田 浩
School of Pharmaceutical Sciences, Showa University
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新井 平八郎
Central Research Laboratories, Zeria Pharmaceutical Co., Ltd.,
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土屋 隆
School of Pharmacy, Hokuriku University
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新井 平八郎
Central Research Laboratories Zeria Pharmaceutical Co. Ltd.
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井下田 浩
School Of Pharmaceutical Sciences Showa University
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土屋 隆
Faculty Of Pharmaceutical Sciences Hokuriku University
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長谷川 博司
School of Pharmaceutical Sciences, Showa University
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長谷川 博司
School Of Pharmaceutical Sciences Showa University
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