Studies on Diazepines. VI. Photolysis of 1H-1,2-Diazepine and Azepine Epidioxides

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概要

• 論文の詳細を見る

• The photolysis of 1H-1,2-diazepine 4,7-epidioxides (1) with a low pressure mercury lamp resulted in the formation of 5-ethoxy-1,3,4-oxadiazoles (3), azoxy compounds (4), and diene compounds (5). A reasonable mechanism for the formation of the products may involve initial isomerization to the 1,2,3-oxadiazoles (8), followed by decomposition and isomerization. However, the azepine 2,5-epidioxide (2) gave only the diene compound (6) in a low yield and did not give any other characterized products.

• 社団法人日本薬学会の論文
• 1978-07-25

著者

• 井下田 浩

  School of Pharmaceutical Sciences, Showa University

• 新井 平八郎

  Central Research Laboratories, Zeria Pharmaceutical Co., Ltd.,

• 土屋 隆

  School of Pharmacy, Hokuriku University

• 新井 平八郎

  Central Research Laboratories Zeria Pharmaceutical Co. Ltd.

• 井下田 浩

  School Of Pharmaceutical Sciences Showa University

• 土屋 隆

  Faculty Of Pharmaceutical Sciences Hokuriku University

• 長谷川 博司

  School of Pharmaceutical Sciences, Showa University

• 長谷川 博司

  School Of Pharmaceutical Sciences Showa University

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