REGIO-SELECTIVE DIAZEPINE FORMATION FROM 3-AZIDOPYRIDINES : THE FIRST EXAMPLES OF MONOCYCLIC 2H-1,4-DIAZEPINES

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概要

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• Photolysis of the 2-substituted 3-azidopyridines (5) having no substituent in the 4-position in the presence of sodium methoxide gave the novel 2H-1,4-diazepines (8), whereas 2-unsubstituted (1) and 2,4-disubstituted 3-azidopyridines (10), upon irradiation under similar conditions, afforded the 5H-1,3-diazepines.

• 社団法人日本薬学会の論文
• 1985-12-25

著者

• 沢西 啓之

  Faculty Of Pharmaceutical Sciences Hokuriku University

• 土屋 隆

  Faculty of Pharmaceutical Sciences, Hokuriku University

• 沢西 啓之

  School of Pharmacy, Hokuriku University

• 土屋 隆

  School of Pharmacy, Hokuriku University

• 土屋 隆

  Faculty Of Pharmaceutical Sciences Hokuriku University

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