Synthesis of 1-Benzometalloles Containing Group 14,15,and 16 Heavier Elements via a Common Dilithiostyrene Intermediate

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概要

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• The Group 14 (Si, Ge, and Sn), Group 15 (P, As, Sb, and Bi), and Group 16 (Se and Te) 2-trimethylsilyl-1-benzometalloles (7) were prepared by the reaction of the corresponding metal reagents with β, o-dilithio-β-trimethyl-silylstyrene intermediate (6), which was derived from phenylacetylene or o-bromoiodobenzene via three steps. The trimethylsilyl group in 7 could be readily removed by treatment with tetrabutylammonium fluoride to give the C-unsubstituted 1-banzometalloles (10).

• 社団法人日本薬学会の論文
• 1994-07-15

著者

• 土屋 隆

  Faculty of Pharmaceutical Sciences, Hokuriku University

• 安池 修之

  Faculty Of Pharmaceutical Sciences Hokuriku University

• 栗田 城治

  Faculty of Pharmaceutical Sciences, Hokuriku University

• 石井 誠

  Faculty of Pharmaceutical Sciences, Hokuriku University

• 土屋 隆

  Faculty Of Pharmaceutical Sciences Hokuriku University

• 栗田 城治

  Faculty Of Pharmaceutical Sciences Hokuriku University

• 石井 誠

  Faculty Of Pharmaceutical Sciences Hokuriku University

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