Studies on Diazepines. XII. Photochemical Synthesis of Novel 1H-1,3-Benzodiazepines from Isoquinoline N-Imides

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概要

• 論文の詳細を見る

• Irradiation of the 1-substituted isoquinoline N-acylimides (3), prepared from isoquinolines (1) by successive N-amination and acylation, brought about a novel photoinduced two-step rearrangement to form the fully unsaturated 1H-1,3-benzodiazepines (4), which were converted into the indole derivative (10) by treatment with acids via the ring-opened intermediate (8) or into (11) upon irradiation presumably via the tricyclic valence isomer (14).

• 公益社団法人日本薬学会の論文
• 1980-09-25

著者

• 岡島 悟

  School Of Pharmacy Hokuriku University

• 岡島 悟

  ヤクルト本社中央研究所

• 土屋 隆

  School of Pharmacy, Hokuriku University

• 円角 美智子

  School of Pharmacy, Hokuriku University

• 土屋 隆

  Faculty Of Pharmaceutical Sciences Hokuriku University

• 円角 美智子

  School Of Pharmacy Hokuriku University

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