Selective Oxidation of 2-Methylnaphthalene to 2-Methyl-1-naphthol by Rhodococcus sp. M192
スポンサーリンク
概要
- 論文の詳細を見る
About 6000 isolates of microorganisms assimilating methylketones (C_3-C_6) were tested for their selective oxidation of 2-methylnaphthalene to 2-methyl-1-naphthol. Strain M192 was the highest 2-methyl-1-naphthol producer and was classified as the genus Rhodococcus. The optimal conditions for the site-specific oxidation were studied using resting Rhodococcus sp. M192. The 2-methyl-1-naphthol productivity was specifically increased using methylethylketone as a carbon source, 1-propanol as a solvent to dissolve the substrate, and ethylxanthate or diethyldithiiocarbamate as an inhibitor of 2-naphthoic acid (side-product) production. In the presence of these compounds, 2-methylnaphthalene was specifically oxidized at the 1-position without the conversion to 2-naphthoic acid. The productivity of 2-methyl-1-naphthol was about 90 μM from 1 mM 2-methylnaphthalene.
- 社団法人日本農芸化学会の論文
- 1996-05-23
著者
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Tani Yoshiki
Graduate School of Biological Sciences, Nara Institute of Science and Technology
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Taguchi Hisataka
Department of Applied Microbial Technology, Faculty of Biotechnology and Life Science, Sojo Universi
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TANI Yoshiki
Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University
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Kita Shinji
Division Of Applied Life Sciences Graduate School Of Agriculture Kyoto University:(present Address)r
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Taguchi H
Department Of Bioresource Development Hiroshima Prefectural University
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Tani Y
Graduate School Of Biological Sciences Nara Institute Of Science And Technology:department Of Biosci
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Tani Yoshiki
Department Of Agricultural Chemistry Kyoto University
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Kobayashi Motoo
Department Of Agricultural Chemistry Faculty Of Agriculture Kyoto University
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KITA Shunbun
Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University
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Kita Shinji
Research Institute, Daiichi Fine Chemical Co.
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Kita Shunbun
Research Institute Daiichi Fine Chemical Co.
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Tani Yoshiki
Department Of Agricultural Chemistry College Of Agriculture Kyoto University
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Taguchi Hisataka
Department Of Applied Microbial Technology Faculty Of Biotechnology And Life Science Sojo University
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