Band Gap Variation of Mn Doped ZnO Films Prepared by Spray Pyrolysis Technique
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概要
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Undoped and manganese doped zinc oxide thin films were prepared on Si(100) substrate using spray pyrolysis technique. Nanorods having random distribution were observed on the ZnO films by scanning electron microscopy. Grazing angle X-ray diffraction and Raman spectroscopy confirmed successful growth of the wurtzite structure Zn1-xMnxO films without any secondary phase. From Raman spectra, the lattice defect was found to increase with increasing Mn concentration. The isothermal magnetization hysteresis measurements at room temperature show that saturation of magnetization decreased with increasing Mn concentration. Optical gap energy determined by the optical reflectance measurement showed a maximum at Mn concentration 10 mol %. It was also found that the strain parameter increases up to 10 mol % and then decreases at 15 mol %. These tendencies seem to be related to the coexistence of Mn3+ and Mn4+ (Mn3+/Mn4+) ions along with the Mn2+ ions in the Zn1-xMnxO films.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2009-06-25
著者
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Soga Tetsuo
Department Of Electronics Faculty Of Engineering Nagoya University
-
Jayavel Ramasamy
Crystal Growth Centre Anna University
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Subramanian Munisamy
Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
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Kumar Ganesan
Centre for Nanoscience and Technology, Anna University, Chennai-600 025, India
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Selvaraj Vijayalakshmi
Crystal Growth Centre, Anna University, Chennai-600 025, India
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Ilanchezhiyan Pugajendy
Centre for Nanoscience and Technology, Anna University, Chennai-600 025, India
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Jayavel Ramasamy
Crystal Growth Centre, Anna University, Chennai-600 025, India
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Soga Tetsuo
Department of Electrical and Computer Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466
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