Phthalocyanine with Trifluoroethoxy Substituents for Organic Solar Cells
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概要
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The properties of soluble zinc phthalocyanines with trifluoroethoxy substituents (TFEO--ZnPcs) were studied to evaluate their possible use in organic thin-film solar cells. We prepared five TFEO--ZnPcs with different numbers and positions of the TFEO substituents. The solubilities, UV--visible absorption spectra, and cyclic voltammograms of these ZnPcs varied with their substituents. TFEO--ZnPc thin-films fabricated by spin-casting exhibited photocurrent generation at wavelengths between 600 and 850 nm. Flat heterojunction solar cells consisting of a poly(3-hexylthiophene) (P3HT) layer as a donor and a TFEO--ZnPc layer as an acceptor exhibited photocurrent generation over a wide range of wavelengths corresponding to both the P3HT and TFEO--ZnPc absorption spectra. The best solar cell performance was obtained with (\beta-TFEO)<inf>4</inf>ZnPc film.
- 2013-05-25
著者
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Shibata Norio
Department Of Applied Chemistry Graduate School Of Engineering Nagoya Institute Of Technology
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Hayashi Yasuhiko
Department Of Cardiology Cardiovascular Center Tsuchiya General Hospital
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Yamada Ichiko
Department of Electrical and Electronic Engineering, Suzuka National College of Technology, Suzuka, Mie 510-0294, Japan
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Iida Norihito
Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
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Soga Tetsuo
Department of Electrical and Computer Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466
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