Novel Cross-linking Compounds Formed through the Reaction of N^α-Acetyltryptophan with Hexanal(Food & Nutrition)
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概要
- 論文の詳細を見る
We separated three N^α-acetyltryptophan (Ac-Trp) derivatives formed through the reaction of Ac-Trp with hexanal, which is a major secondary product of lipid peroxidation. They were identified as 1-[N^1-(N^α-acetyltryptophano)]-1-(N^α-acetyltryptophan-2-yl)hexane (Trp-HL-1), 1,1-bis[N^1-(N^α-acetyltryptophano)]hexane (Trp-HL-2) and 1,1-bis(N^α-acetyltryptophan-2-yl)hexane (Trp-HL-3). Hexanal became a cross-linker between two Ac-Trp molecules on the formation of these compounds. Since Trp-HL-1 contained a newly formed asymmetric carbon atom, its diastereomers, Trp-HL-1a and Trp-HL-1b, were separated and characterized by ORD.
- 社団法人日本農芸化学会の論文
- 1989-10-23
著者
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早瀬 文孝
明治大学農学部農芸化学科
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Hayase Fumitaka
Department of Agricultural Chemistry, Meiji University
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Kato Hiromichi
Department of Agricultural Chemistry, The University of Tokyo
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KANEKO Shigenobu
Department of Wheat and Barley, National Institute of Crop Science, National Agricultural Research O
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Kato H
Univ. Tokyo Tokyo Jpn
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Kato H
Department Of' Agricultural Chemistry The University Of Tokyo
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Kato Hiromichi
Department Of Agricultural Chemistry The University Of Tokyo
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Hayase Fumitaka
Department Of Agricultural Chemistry Faculty Of Agriculture Meiji University
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Hayase Fumitaka
Department Of Agricultural Chemistry The University Of Tokyo:(present Address) Department Of Agricul
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Kaneko Shigenobu
Department Of Agricultural Chemistry The University Of Tokyo
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Hayase F
Department Of Agricultural Chemistry Meiji University
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OKITANI Akihiro
Department of Animal Products Science and Technology, Nippon Veterinary and Zootechnical College
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Okitani A
Faculty Of Veterinary And Animal Science Nippon Veterinary And Animal Science University
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OKITANI Akihiro
Department of Agricultural Chemistry, Faculty of Agriculture, The University of Tokyo
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