Identification of the Modified Structure of Arginine Residues in Proteins with 3-Deoxyglucosone, a Maillard Reaction Intermediate
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概要
- 論文の詳細を見る
The major compounds formed from the N^α-benzoylarginine amide (BzArgNH_2) and 3-deoxyglucosone (3DG) reaction system were purified by reversed-phase HPLC. The major product was identified as R-4-imidazolone (I) ; R=2-(4-benzoylamino-5-pentamide)amino-5-(2,3,4-trihydroxybutyl) as described in a previous paper (ref. 10). Intermediate products to the formation of compound I were identified as R-4(5H)-imidazolone (II), R-4(5-hydroxy)-imidazolone (III), and R-4-dihydroxyl-2-imidazoline (IV). Periodical changes in the amounts of compounds I, II, III, and IV suggest the formation of compound I via compound II by dehydration and oxidation from the BzArgNH_2-3DG reaction system to be the major pathway, the formation of compound I via compound III being the other pathway.
- 社団法人日本農芸化学会の論文
- 1995-08-23
著者
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早瀬 文孝
明治大学農学部農芸化学科
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KONISHI YUTAKA
Department of Cardiovascular Surgery
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早瀬 文孝
日清ファルマ健康科学研究所
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Hayase Fumitaka
Department of Agricultural Chemistry, Meiji University
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Kato Hiromichi
Department of Agricultural Chemistry, The University of Tokyo
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Kato H
Department Of Agricultural Chemistry The University Of Tokyo
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Kato H
Department Of Food Science Otsuma Women's University
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Kato Hiromichi
Department Of Agricultural Chemistry The University Of Tokyo
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Kato Hiromichi
Department Of Food Science Ohtsuma University
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Kato H
Otsuma Women's Univ. Tokyo Jpn
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Hayase Fumitaka
Department Of Agricultural Chemistry Faculty Of Agriculture Meiji University
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Hayase Fumitaka
Department Of Agricultural Chemistry The University Of Tokyo:(present Address) Department Of Agricul
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Hayase Fumitaka
Department Of Agricultural Chemistry The University Of Tokyo : (present Address) Department Of Agric
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Hayase Fumitaka
Central Research Laboratories Asahi Breweries Ltd.
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Konishi Yuko
Department Of Applied Chemistry Faculty Of Engineering Nagasaki University
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Kato H
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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Hayase F
Department Of Agricultural Chemistry Meiji University
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Konishi Y
Kirin Brewery Co. Ltd. Gunma Jpn
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Kato Hiroshi
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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Hayase Fumitaka
Dep. Of Agricultural Chemistry Fac. Of Agriculture Meiji Univ.
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