Studies on Organic Fluorine Compounds. XXXI. Oxidative Coupling of Ketone Enolates and Trimethylsilyl Enol Ethers by Means of Cu(OTf)_2
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概要
- 論文の詳細を見る
The oxidative coupling of ketone enolates and trimethylsilyl enol ethers by means of cupric trifluoromethanesulfonate [Cu(OTf)_2] is described in detail. 1,4-Diketones were effectively prepared by treating lithium enolates with Cu(OTf)_2 in i-PrCN. 1,3-Cyclopentanedione derivatives were synthesized through intramolecular coupling of 2,4-pentanedione derivatives. Treatment of trimethylsilyl enol ethers with Cu(OTf)_2 in i-PrCN also afforded the corresponding coupling products.
- 公益社団法人日本薬学会の論文
- 1980-01-25
著者
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田口 武夫
東京薬科大学薬学部
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小林 義郎
Tokyo College of Pharmacy
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田口 武夫
Tokyo College of Pharmacy
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小林 義郎
東京薬科大学薬学部
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森川 勉
Tokyo College of Pharmacy
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森川 勉
東京薬科大学薬学部
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得能 悦子
Tokyo College Of Pharmacy
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関口 尚
Tokyo College of Pharmacy
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