Studies on Organic Fluorine Compounds. XLIII. The Ene Reaction of Hexafluoroacetone
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概要
- 論文の詳細を見る
The reaction of hexafluoroacetone with phenyl-substituted allyl compounds was found to give the ene products. Thus, allylbenzene gave 1,1,1-trifluoro-5-phenyl-2-(trifluoromethyl) pent-4-en-2-ol. Allyl phenyl ether and thioether gave the corresponding ene products. The product from the latter cyclized to 5-phenylthio-2,2-bis (trifluoromethyl) tetrahydrofuran. N-Allyl-N-methylaniline reacted with the ketone to give the 4-(1,1,1,3,3,3-hexafluoro-2-hydroxy-2-propyl) derivative via the Friedel-Crafts reaction, and this compound further reacted in the ene reaction to give unusual products.
- 社団法人日本薬学会の論文
- 1984-12-25
著者
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小林 義郎
Tokyo College of Pharmacy
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小林 義郎
東京薬科大学薬学部
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熊懐 稜丸
摂南大・薬
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永井 隆文
Faculty Of Pharmaceutical Sciences Setsunan University
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熊懐 稜丸
Faculty of Pharmaceutical Sciences, Setsunan University
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熊懐 稜丸
摂南大薬
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熊懐 稜丸
Faculty Of Pharmaceutical Sciences Setsunan University
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熊懐 稜丸
Faculty Of Pharmaceutical Sciences Kyushu University:(present Address)tokyo College Of Pharmacy Kash
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