TRIFLUOROMETHYLATED ALLYLIC ANION AND RADICAL : GENERATION BY THE ELECTRONIC INVERSION OF II-ALLYLICPALLADIUM COMPLEX BY SAMARIUM DIIODIDE
スポンサーリンク
概要
- 論文の詳細を見る
Trifluoromethylated π-allylic Pd-complex was treated with samarium diiodide to generate the trifluoromethylated allylic anion and radical species.
- 公益社団法人日本薬学会の論文
- 1990-04-25
著者
-
田口 武夫
東京薬科大学薬学部
-
小林 義郎
Tokyo College of Pharmacy
-
田口 武夫
Tokyo College of Pharmacy
-
小林 義郎
東京薬科大学薬学部
-
Taguchi T
Department Of Pathobiochemistry Faculty Of Pharmacy Meijo University
-
榛澤 雄二
Tokyo College of Pharmacy
-
石澤 誠二
Tokyo College of Pharmacy
-
榛澤 雄二
東京薬科大学薬学部
関連論文
- Quantitative Structure-in Vivo Half-Life Relationships of Perfluorochemicals for Use as Oxygen Transporters
- Amino Acids and Peptides. XXIII. Leu-Enkephalin Analogs Containing a Fluorinated Amino Acid at Position 2,4 or 5
- Effect of Chitobiose and Chitotriose on Carbon Tetrachloride-Induced Acute Hepatotoxicity in Rats(Pharmacology)
- Pharmacokinetics of Chitobiose and Chitotriose Administered Intravenously or Orally to Rats(Biopharmacy)
- Antioxidant Activities of Chitobiose and Chitotriose(Miscellaneous)
- Structure-Activity Relationship of Fluorine-Containing Renin Inhibitory Peptides Based upon the Tertiary Structure of Human Renin
- Synthesis and Biological Activity of Fluorine-Modified Platelet Activating Factors(Medicinal Chemistry,Chemical)
- PREPARATION OF (22S)- AND (22r)-24-HOMO-26,26,26,27,27,27-HEXAFLUORO-1,22,25-TRIHYDROXY-24-YNE-VITAMIN D_3
- Studies on Organic Fluorine COmpounds. IL. The Ene Reaction of Trifluoroacetone
- Studies on Organic Fluorine Compounds. XLIII. The Ene Reaction of Hexafluoroacetone
- Studies on Organic Fluorine Compounds. XLI. The Friedel-Crafts Reaction of Trifluoropropene
- Synthesis and Biological Activity of 1α-Fluoro-25-hydroxyvitamin D_3
- Studies on Organic Fluorind Compounds. LII : Synthesis and Biological Activity of 26,26,26,27,27-Pentafluoro-1α-hydroxy-27-methoxyvitamin D_3
- Studies on Organic Fluorine Compounds. II. Mass Spectrometry of Trifluoromethylated Pyridines.
- Syntheses of Ten-membered Ring Amine Derivatives and 1-Azabicyclo-[4,4,1] undecane from 3,4,6,7,8,9-Hexahydro-2H-quinolizine
- Studies on the Reaction of Heterocyclic Compounds. XV. N-Alkylation of 1,2,3,4-Tetrahydro-5-methyl-1,6-naphthyridine
- Studies on the Reactions of Heterocyclic Compounds. XIV. 1,3-dipolar Cycloaddition of Some Isoquinolinium Ylides with Methyl Propiolate
- STEREOSELECTIVE SYNTHESIS OF TRIFLUOROMETHYLATED OLEFIN AND DIENE
- Studies on Organic Fluorine Compounds. XLVII. Synthesis of Trifluoromethylated Sugars through the Aldol Reaction of 2-Trimethylsilyloxy-4-trifluoromethylfuran
- フッ素と薬学
- Studies on Organic Fluorine Compounds. VII. Trifluoromethylation of Aromatic Compounds
- Studies on Organic Fluorine Compounds. XLVI. Synthesis of 4-Trifluoromethyl-2 (5H)-furanone and 4-Trifluoromethyl-N-substituted Dihydropyrrol-2-ones
- Studies on Organic Fluorine Compounds. XLV. Synthesis and Regioselective Substitution Reaction of 3-Trifluoromethylfuran
- SYNTHESIS OF TRIFLUOROMETHYLATED LACTONE AND EPOXIDE
- RADICAL CYCLIZATIONS TO FLUOROOLEFINS
- 有機フッ素化合物の合成と反応 : 30年の研究を振り返って
- Preparation and Biological Activity of 24-Epi-26,26,26,27,27,27-hexafluoro-1α, 25-dihydroxyvitamin D_2
- TRIFLUOROMETHYLATION OF CHIRAL ALDEHYDE AND SYNTHESIS OF 6-DEOXY-6,6,6-TRIFLUOROHEXOSES
- Synthesis of Fluorinated Retinal : A C_6-C_7 s-trans Fixed Retinal Containing a Trifluoromethyl Group at the Terminal Position of the Conjugated System
- TRIFLUOROMETHYLATED ALLYLIC ANION AND RADICAL : GENERATION BY THE ELECTRONIC INVERSION OF II-ALLYLICPALLADIUM COMPLEX BY SAMARIUM DIIODIDE
- PALLADIUM(0)-CATALYZED REACTIONS OF TRIFLUOROMETHYLATED ALLYLIC ESTER DERIVATIVES : SYNTHESIS OF TRIFLUOROMETHYLATED CHRYSANTHEMIC ACID ESTER
- ENANTIOSELECTIVE REDUCTION OF FLUOROALKYL ALKYNYL KETONES : ENORMOUS ELECTRONIC EFFECT OF THE TRIFLUOROMETHYL GROUP(Communications to the Editor)
- SYNTHESIS OF 5-FLUOROARACHIDONIC ACID AND ITS BIOTRANSFORMATION TO 5-FLUORO-12-HYDROXYEICOSATETRAENOIC ACID(Communications to the Editor)
- KINETIC RESOLUTION OP FLUORQALKYL (E)-VINYL CARBINOL DERIVATIVES BY ASYMMETRIC EPOXIDAT1QN WITH TITANIUM-TARTRATE CATALYSTS(Communications to the Editor)
- Studies on Organic Fluorine Compounds. L. Synthesis and Biological Activity of 2α-Fluorovitamin D_3
- Trifluoromethylation with Bromotrifluoromethane
- Studies on Organic Fluorine Compounds. XLIV. The Diels-Alder Reaction of Trifluoromethylated Cyclopropenyl Ketone and Its Imine
- γ, γ-ジアルコキシアリルジルコニウム種を用いた炭素-炭素結合形成反応の開発
- γ,γ-ジアルコキシアリルジルコニウム種を用いた炭素-炭素結合形成反応の開発
- 雑感
- アシルジルコノセン錯体を求核的アシル基供与体とする炭素-炭素結合形成反応
- 奨励賞受賞 伊藤久央氏の業績
- フッ素系生物活性物質 : フッ素の特異性と医薬品開発
- 光学活性アトロプ異性アニリド誘導体の合成と不斉反応への応用
- 学術貢献賞受賞伊関克彦氏の業績
- ハロ環化中間体形成を活性化手法として用いる有機合成反応の開発
- フッ素置換基を有するラジカル環化系の反応
- ヨードカルボ環化反応
- ジルコノセン錯体を用いた炭素-炭素結合形成反応の新展開
- Simmons-Smith Reactions of Fluoroallyl Alcohol Derivatives
- 小林義郎先生紫綬褒章受賞
- Studies on the Organic Fluorine Compounds. XXIV. Photochemical Trifluoromethylation of Aromatic Compounds
- Studies on Organic Fluorine Compounds. XXI. Isomerization of Fluorinated Dewar Pyridine Derivative and Its Metal Complexes
- Studies on Organic Fluorine Compounds. XX. Synthesis and Reactions of a Substituted Dewar Pyridine
- Studies on Organic Fluorine Compounds. XIX. Synthesis and Reactions of"Dewar"Thiophene
- Studies on Organic Fluorine Compounds. XVI. : Stereochemistry in Fluorination of Sterols with Phenylfluorophosphoranes
- Studies on Organic Fluorine Compounds. XIII. Studies on Equilibrium of (Trifluoro- and/or Chlorodifluoromethyl)-dihydro-s-triazine Derivatives by ^F-Nuclear Magnetic Resonance Spectra
- Studies on Organic Fluorine Compounds. XII. Photolysis of (Fluoroalkyl)-s-triazines
- Studies on Organic Fluorine Compounds. XI. Reaction of Arylfluorophosphoranes with Alcohols
- Studies on Organic Fluorine Compounds. XLII. Synthesis and Reactions of Phenyltrifluoromethylacetylenes
- Studies on Organic Fluorine Compounds. XXII. Synthesis and Reactions of (Trifluoromethyl) benzofurans
- Studies on Organic Fluorine Compounds. XVIII. On the Mechanism of the Conversion of Trifluoromethyl Group to Amino Group on a Quinoline Ring
- Studies on Organic Fluorine Compounds. XVII. Reaction of Benzotrifluoride Derivatives with Sodium Amide
- Studies on the Reactions of Heterocyclic Compounds. XIII. Basicity of 1,6-Naphthyridine and Its N-Oxides : Correlation to Peracid Oxidation
- Studies on the Reaction of Heterocyclic Compounds. XII. N-Oxidation of Diazabenzene and Diazanaphthalene
- Photolysis of 2-(Trifluoromethyl) quinoline 1-Oxides and 1-(Trifluoromethyl) isoquinoline 2-Oxide
- Synthese von Derivaten der Cinchona-Alkaloide. XXXIII. Synthese von 2'-Cyanoderivaten der Alkaloide der Chinin-Reihe
- Studies on the Reactions of Heterocyclic Compounds. X. 1,3-Dipolar Cycloaddition Reaction of Isoquinolinium Ylides and Dicyanoacetylene
- Studies on the Reactions of Heterocyclic Compounds. IX. Syntheses of 1,10b-Dihydropyrrolo[2,1-α]isoquinolines and 2,3-Dihydropyrrolo[2,1-α]isoquinolines
- Studies on the Reactions of Heterocyclic Compounds. VI. 1,3-Dipolar Cycloaddition Reaction of Disubstituted Methylides of Isoquinoline and Pyridine with Acetylenic Compounds
- Studies on the Reactions of Heterocyclic Compounds. VIII. 1,3-Dipolar Cycloaddition Reaction of Isoquinolinium Cyano (methoxycarbonyl)-methylide with Dimethyl Acetylenedicarboxylate : Structure and Reaction of the Adduct
- STEREOSELECTIVE SYNTHESIS OF gem-BISTRIFLUOROMETHYLCYCLOPROPANE DERIVATIVES
- Studies on Organic Fluorine Compounds. XXXI. Oxidative Coupling of Ketone Enolates and Trimethylsilyl Enol Ethers by Means of Cu(OTf)_2
- Studies on Organic Fluorine Compounds. IV. Conversion of Alcohols to Fluorides by Diphenyltrifluorophosphorane
- Studies on Organic Fluorine Compounds. III. Conversion of Alcohols to Fluorides by Difluorotriphenylphosphorane
- Studies on Organic Fluorine Compounds. LIV. : Synthesis of 2,2-Difluoroarachidonic Acid
- Studies on Organic Fluorine Compounds. XL. Ring-Opening Reactions of gem-Difluorocyclopropyl Carbinols
- Studies on Organic Fluorine Compounds. XXXIX. Studies on Steroids. LXXIX. Synthesis of 1α, 25-Dihydroxy-26,26,26,27,27,27-hexafluorovitamin D_3
- Studies on the Reactions of Heterocyclic Compounds. XI. Methylation of Heteroaromatic N-Oxides
- Oxidative Cyanation of Aromatic Amine Oxides
- Studies on the Reactions of Heterocyclic Compounds. III. Cyanation of 1,6-Naphthyridine N-Oxides
- Studies on the Reactions of Heterocyclic Compounds. I. Syntheses and Some Reactions of 1,6-Naphthyridine N-Oxides
- Synthesis and Biological Activities of Novel Antiallergic Agents with 5-Lipoxygenase Inhibiting Action.
- Synthesis of Benzimidazole Derivatives as Antiallergic Agents with 5-Lipoxygenase Inhibiting Action
- Studies on the Reactions of Heterocyclic Compounds. V. Syntheses of Diazinium Ylides and Their Conversion to Azaindolizines
- Studies on the Reactions of Heterocyclic Compounds. IV. Preparations and Reactions of Heterocyclic N-Ylides
- 7.規那塩基の変換
- 含フッ素生理活性物質の合成
- ジルコノセン錯体を用いた炭素一炭素結合形成反応の新展開
- Studies on Organic Fluorine Compounds. X. Reaction of Trifluoromethyl Group in Heterocycles with Sodium Amide
- 1-PHENYLSULFONYL-3,3,3-TRIFLUOROPROPENE I : THE MICHAEL-TYPE ADDITION REACTION
- 有機フッ素化合物と生理活性
- gem-ジフルオロシクロプロパン誘導体の開環反応を用いるフルオロオフレィン類の合成 (フッ素の化学とその応用)
- ビタミンD3のフッ素による化学修飾
- Studies on the Reactions of Heterocyclic Compounds. II. Syntheses and Some Reactions of 1,6-Phenanthroline N-Oxides
- Studies on organic fluorine compounds.-1,2-
- Synthese von Derivaten der Cinchona-Alkaloide. XXX. Ableitung einer Verbindung mit dem Tetrahydro-β-carbolin-Ring aus Chinin.
- Synthese von Derivaten der Cinchona-Alkaloide. XXIX. Uber Dihydroepinichin und seine Acylwanderung.
- Ableitung einer Verbindung mit dem Tetrahydro-β-carbolin-Ring aus Chinin
- Studies on Organic Fluorine Compounds. XXX. Ring Opening Reaction of Acetoxydifluorocyclopropanes with Various Nucleophiles