Studies on Organic Fluorine Compounds. XLIV. The Diels-Alder Reaction of Trifluoromethylated Cyclopropenyl Ketone and Its Imine
スポンサーリンク
概要
- 論文の詳細を見る
The thermolysis of 1,5,6,7-tetrakis (trifluoromethyl)-2,3,4-triazabicyclo [3.2.0] hepta-2,6-diene (3) without a solvent gave 1-[1,2,3-tris (trifluoromethyl) cyclopropenyl]-2,2,2-trifluoroethylimine (2). The flash vacuum pyrolysis of 3 gave 1,2,3-tris (trifluoromethyl) cyclopropene (6). 1,2,3,4-Tetrakis (trifluoromethyl) pyrrole (5) was produced in both reactions. 1,2,3-Tris (trifluoromethyl) cyclopropen-3-yl trifluoromethyl ketone (1) and 2 were found to react as good dienophiles and gave products obtained through the transition states where the electron-deficient part of the dienophiles attracted the electron-rich part of the diene components, a hetero atom or the diene moiety.
- 公益社団法人日本薬学会の論文
- 1985-09-25
著者
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小林 義郎
Tokyo College of Pharmacy
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吉田 力
Tokyo College Of Pharmacy
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小林 義郎
東京薬科大学薬学部
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熊懐 稜丸
摂南大・薬
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安藤 章
摂南大学薬学
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熊懐 稜丸
Faculty of Pharmaceutical Sciences, Setsunan University
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中島 正晴
Tokyo College of Pharmacy
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榛沢 雄二
Tokyo College of Pharmacy
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安藤 章
Tokyo College of Pharmacy
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熊懐 稜丸
摂南大薬
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熊懐 稜丸
Faculty Of Pharmaceutical Sciences Setsunan University
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熊懐 稜丸
Faculty Of Pharmaceutical Sciences Kyushu University:(present Address)tokyo College Of Pharmacy Kash
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