ENANTIOSELECTIVE REDUCTION OF FLUOROALKYL ALKYNYL KETONES : ENORMOUS ELECTRONIC EFFECT OF THE TRIFLUOROMETHYL GROUP(Communications to the Editor)
スポンサーリンク
概要
- 論文の詳細を見る
Fluoroalkyl alkynyl ketones(<1a>__〜-c) were reduced enantioselectively by (R)-BINAL-H and (S)-Alpine-Borane to give optically active alcohols (<2a>__〜-c). In the BINAL-H reduction, the trifluoromethyl group exerted an electronic effect on the enantioselectivity of the reagent.
- 公益社団法人日本薬学会の論文
- 1987-06-25
著者
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小林 義郎
Tokyo College of Pharmacy
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小林 義郎
東京薬科大学薬学部
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川越 敬一
Tokyo College Of Pharmacy
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榛沢 雄二
Tokyo College of Pharmacy
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