Chemical Structures of Hetero-oligosaccharides Produced by Arthrobacter sp. K-1β- Fructofuranosidase

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概要

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• The structures of hetero-oligosaccharides obtained by the action of transglycosylation of Arthrobacter sp. K-1 β-fructofuranosidase, using sucrose as the fructosyl donor, and several mono- and di-sacchrides as the acceptors were investigated. The main transfer products to most reducing mono- and di-sacchrides were non-reducing oligosaccharides with a fructosyl residue linked to a hemiacetal hydroxyl group. In the presence of L-sorbose, the enzyme produced 2-O-β-D-fructofuranosyl-α-L-sorbopyranoside as the major product. With D-galactose or L-arabinose, the enzyme produced not only non-reducing oligosaccharides, but also reducing oligosaccharides, which were identified as 3-O-β-D-fructofuranosyl-D-galactopyranose and 4-O-β-D-fructofuranosyl-L-arabinopyranose, respectively. When a non-reducing sugar such as methyl α-glucoside was used as an acceptor, the product formed had a fructosyl residue linked at the C6 hydroxyl group.

• 社団法人日本農芸化学会の論文
• 1994-02-23

著者

• Fujita K

  Kyoto Prefectural Univ. Kyoto Jpn

• Koizumi K

  School Of Pharmaceutical Sciences Mukogawa Women's University

• Koizumi Kyoko

  Faculty Of Pharmaceutical Sciences Mukogawa Women's University

• MINAMIURA Noshi

  Faculty of Science, Osaka City University

• Iizuka Masaru

  Faculty Of Science Osaka City University

• Iizuka Masaru

  Department Of Bio- And Geo-science Graduate School Of Science Osaka City University

• FUJITA Koki

  Carbohydrate Research Laboratory, Ensuiko Sugar Refining Co., Ltd.

• KUWAHARA Nobuhiro

  Carbohydrate Research Laboratory, Ensuiko Sugar Refining Co., Ltd.

• TANIMOTO Toshiko

  Faculty of Pharmaceutical Sciences, Mukogawa Women's University

• Kuwahara Nobuhiro

  Carbohydrate Research Laboratory Ensuiko Sugar Refining Co. Ltd.

• Kitahata S

  Department Of Bioscience And Biotecnology Shinshu University

• Furuichi Kimiaki

  Faculty of Science,Osaka City University

• Minamiura N

  Department Of Bio- And Geo-science Graduate School Of Science Osaka City University

• Minamiura Noshi

  Faculty Of Science Osaka City University

• Iizuka M

  Department Of Bio- And Geo-science Graduate School Of Science Osaka City University

• Kitahata Sumino

  Osaka Municipal Technical Research Institute

• Furuichi K

  Bio Research Corporation Of Yokohama

• Fujita Koki

  Carbohydrate Research Laboratory Ensuiko Sugar Refining Co. Ltd.

• Tanimoto T

  School Of Pharmaceutical Sciences Mukogawa Women's University

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