Esterification of Glycosides by a Mono- and Diacylglycerol Lipase from Penicillium camembertii and Comparison of the Products with Candida cylindracea Lipase

スポンサーリンク

概要

• 論文の詳細を見る

• Glycosides with glycerol and trimethylolpropane (TMP) moieties at the reducing ends were esterified by mono- and diacylglycerol lipase from Penicillium camembertii. Several TMP glycosides were esterified to a greater extent than those of glycerol. The products from glucosyl TMP and oleic acid by Penicillium and Candida cylindracea lipases were isolated and their structures elucidated. The lipases formed two monoesters; a major monoester whose TMP moiety was esterified and a minor monoester bearing an oleic acid group at the glucose moiety. One of the two diesters has a diacylated TMp moiety, while the other has acyl groups at both TMP and glucose moieties. Candida lipase formed these diesters in an almost equal ratio. Penicillium lipase formed the latter one preverentially. Candida lipase synthesized tri- and tetraesters, which accounted for about 34% of all the products, while Penicillium lipase formed these highly esterified products at a level of only 4% of the total products.

• 社団法人日本生物工学会の論文
• 1995-07-25

著者

• Tominaga Y

  Dep. Of Applied Biochemistry And Food Sci. Saga Univ.

• Yanagita Teruyoshi

  Lab. Of Nutrition Biochemistry Dep. Of Applied Biochemistry And Food Sci. Saga Univ.

• NAKAMURA Masaki

  Osaka Municipal Technical Research Institute

• Shimada Y

  Department Of Biochemistry Osaka Municipal Technical Research Institute

• Shimada Y

  Department Of Physics Chuo University:tecmo

• Shimada Yuji

  Osaka Municipal Technical Research Institute

• KITAHATA Sumio

  Osaka Municipal Technical Research Institute

• TOMINAGA Yoshio

  Osaka Municipal Technical Research Institute

• NAKANO HIROFUMI

  Osaka Municipal Technical Research Institute, and Yashiro Co, Ltd.,

• Yanagita Teruyoshi

  Dep. Of Applied Biochemistry And Food Sci. Saga Univ.

• Kitahata S

  Department Of Bioscience And Biotecnology Shinshu University

• Tominaga Yoshio

  The Organ Transplant Center Nagoya Second Red Cross Hospital

• Nakano Hirofumi

  Osaka Municipal Technical Research Institute

• Nakamura Masaki

  Osaka Municipal Technical Res. Inst.

• Nakano Hirofumi

  Department Of Chemistry Faculty Of Science Osaka University

関連論文

• Preparation and Properties of Bis(sodium sulfate) Types of Cleavable Surfactants Derived from Diethyl Tartrate
• Synthesis and Properties of Soap Types of Double-Chain Cleavable Surfactants Derived from Pyruvate
• 2つのエステル基を有するビス第4級アンモニウム塩型分解性界面活性剤の合成と物性
• Emulsion Polymerization by Using Chemocleavable Emulsifiers Derived from 1-O-Alkylglycerols
• Purification and Characterization of a Novel Cholesterol Esterase from Pseudomonas aeruginosa, with Its Application to Cleaning Lipid-stained Contact Lenses(Biochemistry & Molecular Biology)
• The 9cis, 11trans, 13cis Isomer of Conjugated Linolenic Acid Reduces Apolipoprotein B100 Secretion and Triacylglycerol Synthesis in HepG2 Cells
• S-Propyl-Cysteine Sulfoxide and DL-Methionine Sulfoxide Inhibit the Secretion of Apolipoprotein B100 and Lipids in HepG2 Cells
• Conjugated Fatty Acids in Food and Their Health Benefits
• Further Study on the 1,4-α-Transglucosylation of Rubusoside, a Sweet Steviol-Bisglucoside from Rubus suavissimus(Organic Chemistry)
• Production of Stevioside and Rubusoside Derivatives by Transfructosylation of β-Fructofuranosidase(Biological Chemistry)
• Production of Rubusoside Derivatives by Transgalactosylation of Various α-Galactosidases(Biological Chemistry)
• Production of Rubusoside Derivatives by Transgalactosylation of Various β-Galactosidases(Biological Chemistry)
• Isomer-Specific Anti-Obese and Hypolipidemic Properties of Conjugated Linoleic Acid in Obese OLETF Rats
• Short-Term Feeding of Conjugated Linoleic Acid Does Not Induce Hepatic Steatosis in C57BL/6J Mice
• Alleviation of Fatty Liver by α-Linolenic Acid
• Purification of Conjugated Linoleic Acid Isomers through a Process Including Lipase-catalyzed Selective Esterification(Biochemistry & Molecular Biology)
• Conjugated Linoleic Acid Reduces Hepatic Microsomal Triacylglycerol Transfer Protein Activity and Hepatic Triacylglycerol Mass in Obese Rats
• Comparison of the Effects of Triacylglycerol-CLA and Free Fatty Acid-CLA on Hepatic Lipid Metabolism in OLETF Obese Rats
• Methyl Esterification of Waste Fatty Acids with Immobilized Candida antarctica Lipase
• A New Type of Aminoacyltransferase from Saccharothrix sp. AS-2 Favorable for the Synthesis of D-Amino Acid-Containing Peptides
• Ethyl Esterification of Docosahexaenoic Acid in an Organic Solvent-Free System with Immobilized Candida antarctica Lipase
• A Novel α-Amino-Acid Esterase from Bacillus mycoides Capable of Forming Peptides of DD- and DL-Configurations
• Enzymatic Purification of Polyunsaturated Fatty Acids
• 固定化Rhizomucor mieheiリパーゼによる選択的アルコリシス反応を利用したドコサヘキサエン酸エチルの精製
• Amino Acid Residues Contributing to Stabilization of Fusarium heterosporum Lipase
• Stepwise Ethanolysis of Tuna Oil Using Immobilized Candida antarctica Lipase
• C-Terminal Peptide of Fusarium heterosporum Lipase Is Neccessary for Its Incrrreasing Thermostability
• Enrichment of Ethyl Docosahexaenoate by Selective Alcoholysis with Immobilized Rhizopus delemar Lipase
• Fatty Acid Specificity of Rhizopus delemar Lipase in Acidolysis
• Penicillium abeanum Lipase : Purification, Characterization, and Its Use for Docosahexaenoic Acid Enrichment of Tuna Oil
• Expression of Lipase cDNA from Fusarium heterosporum by Saccharomyces cerevisiae : High-Level Production and Purification
• Inhibition of β-Fructofuranosidases and α-Glucosidases by Synthetic Thio-fructofuranoside(Biochemistry & Molecular Biology)
• Enzymatic Synthesis of N-Acetylglucosaminyl-cyclodextrin by the Reverse Reaction of N-Acetylhexosaminidase from Jack Bean
• Synthesis of 6-O-α-D-Galactosyl α-Cyclodextrin by Coffee Bean α-Galactosidase
• Acceptor Specificity of Cyclodextrin Glycosyltransferase from Bacillus stearothermophilus and Synthesis of α-D-Glucosyl O-β-D-galactosyl-(1→4)-β-D-glucoside
• Galactosylation at Side Chains of Branched Cyclodextrins by Various β-Galactosidases
• Enzymic Synthesis of 4^5-O-β-Galactosyl-maltopentaose by Bacillus circulans β-Galactosidase(Biological Chemistry)
• Transfructosylation Catalyzed by β-Fructofurariosidase I from Arthrobacter sp. K-1(Biological Chemistry)
• Purification and Some Properties of β-Fructofuranosidase I from Arthrobacter sp. K-1(Biological Chemistry)
• Preparation and Properties of Novel Double-Chain Nonionic Surfactants with Acid Decomposition Function
• Synthesis of Glycosyl Glycerol by Cyclodextrin Glucanotransferases(ENZYMOLOGY,PROTEIN ENGINEERING,AND ENZYME TECHNOLOGY)
• Hydrolysis of β-Glucosyl Ester Linkage of p-Hydroxybenzoyl β-D-Glucose, a Chemically Synthesized Glucoside, by β-Glucosidases
• Synthesis of Novel Heterobranched β-Cyclodextrins from α-D-Mannosyl Maltotriose and β-Cyclodextrin by the Reverse Action of Pullulanase, and Isolation and Characterization of the Products
• Hydrolysis of β-Galactosyl Ester Linkage by β-Galactosidases
• Transfructosylation of Thiol Group by β-Fructofuranosidases
• Synthesis of Novel Heterobranched β-Cyclodextrins from 4^2-O-β-D-Galactosyl-Maltose and β-Cyclodextrin by the Reverse Action of Pullulanase, and Isolation and Characterization of the Products
• Galactosylation of Thiol Group by β-Galactosidase
• Purification and Some Properties of a β-Glucosidase from Flavobacterium johnsonae
• Purification and Characterization of a Novel β-Glucosidase from Clavibacter michiganense That Hydrolyzes Glucosyl Ester Linkage in Steviol Glycosides
• Enzymatic Synthesis of Oligosaccharides Containing Galβ→4Gal Disaccharide at the Non-Reducing End Using β-Galactanase from Penicillium citrinum
• Enzymatic Synthesis of Mannosyl-cyclodextrin by α-Mannosidase from Jack Bean
• Synthesis of 2-Deoxy-glucooligosaccharides through Condensation of 2-Deoxy-D-glucose by Glucoamylase and α-Glucosidase
• Esterification of Glycosides by a Mono- and Diacylglycerol Lipase from Penicillium camembertii and Comparison of the Products with Candida cylindracea Lipase
• Reaction Conditions for the Production of γ-Cyclodextrin by Cyclodextrin Glucano-transferase from Brevibacterium sp. No.9605
• Transgalactosylation Catalyzed by α-Galactosidase from Candida guilliermondii H-404
• Enzymatic Synthesis of α-Linked Galactooligosaccharides Using the Reverse Reaction of a Cell-bound α-Galactosidase from Candida guilliermondii H-404
• Galactosylation of Cyclodextrins and Branched Cyclodextrins by α-Galactosidases
• Purification and Some Properties of α-Galactosidase from Candida guilliermondii H-404
• Purification and Some Properties of α-Galactosidase from Pseudomonas fluorescens H-601(Biological Chemistry)
• Purification and Some Properties of Dextrin Dextranase from Acetobacter capsulatus ATCC 11894
• Vibration Exposure and Symptoms in Postal Carriers Using Motorbikes
• Production of Structured Lipid Containing Docosahexaenoic and Caprylic Acids Using Immobilized Rhizopus delemar Lipase
• Morphological Diversity of the Colony Produced by Bacteria Proteus mirabilis
• Spatiotemporal Patterns Produced by Bacteria
• Pretreatment of Immobilized Candida antarctica Lipase for Biodiesel Fuel Production from Plant Oil
• Biodiesel Fuel Production from Plant Oil Catalyzed by Rhizopus oryzae Lipase in a Water-Containing System without an Organic Solvent
• Fractionation of Conjugated Linoleic Acid Isomers by Selective Hydrolosis with Candida rugosa Lipase
• Purification and Some Properties of a Levanase from Streptomyces sp. No. 7-3(Biological Chemistry)
• The Acceptor Specificity of Amylomaltase from Escherichia coli IFO 3806(Biological Chemistry)
• Purification and Some Properties of a Protease from Streptomyces limosus
• Purification and Characterization of a Carboxylesterase from Pseudomonas sp. KWI-56
• Purification and Characterization of a Novel Solvent-Tolerant Lipase from Fusarium heterosporum
• Synthesis of Polyunsaturated Fatty Acid L-Menthyl Esters through Lipase-Catalyzed Esterification in an Organic Solvent-Free System
• Transfer Reaction Catalyzed by Exo-β-1,4-galactanase from Bacillus subtilis(Biological Chemistry)
• Lipase-Catalyzed Esterification of Mono- and Oligoglycosides with Various Fatty Acids
• Purification and Characterization of a New Type of α-Glucosidase from Paecilomyces lilacinus That Has Transglucosylation Activity to Produce α-1,3- and α-1,2-Linked Oligosaccharides(Biochemistry & Molecular Biology)
• Cloning, Nucleotide Sequencing, and Expression in Escherichia coli of a Lipase and Its Activator Genes from Pseudomonas sp. KWI-56(Biological Chemistry)
• Physiological Effects of Dietary PIPS Soybean-Derived Phospholipid in Obese Zucker (fa-fa) Rats
• The Sulfated Polysaccharide Porphyran Reduces Apolipoprotein B100 Secretion and Lipid Synthesis in HepG2 Cells
• Effect of Vaccinium ashei reade Leaves on Lipid Metabolism in Otsuka Long-Evans Tokushima Fatty Rats
• Syntheses of Glucosides with Trimethylolpropane and Two Related Polyol Moieties by Cyclodextrin Glucanotransferase and Their Esterification by Lipase
• Structure of Di-O-α-Maltosyl Cyclodextrins Produced from α-Maltosylfluoride and Cyclodextrins(Biological Chemistry)
• Effects of Temperature on 6-O-α-Maltosyl Cyclodextrin Production from α-Maltosylfluoride and Cyclodextrins(Biological Chemistry)
• Purification and Some Properties of a New Levanase from Bacillus sp. No. 71
• Purification and Some Properties of a Trehalase from a Green Alga, Lobosphaera sp.
• Purification and Properties of Cyclodextrin Glucanotransferase from Brevibacterium sp. No. 9605
• Formation of Trehalose and Its 2-Deoxy Analogs through Condensation by a Trehalase from Lobosphaera sp.
• Induction of Geotrichum candidum Lipase by Long-Chain Fatty Acids
• Purification and Properties of Carboxylesterase from Ochrobactrum anthropi(Biological Chemistry)
• Esterification of Glycosides with Glycerol ant Trimethylolpropane Moieties by Candida cylidracea Lipase(Biological Chemistry)
• Enhanced Stability of a Microbial Lipase Immobilized to a Novel Synthetic Amine Polymer(Biological Chemistry)
• Purification and Characterization of Aspergillus niger Lipase(Biological Chemistry)
• Purification and Some Properties of Amylomaltase from Escherichia coli IFO 3806(Biological Chemistry)
• Production of Diglycerol Conjugated Linoleic Acid Monoester by Esterification with Penicillium camembertii Lipase
• Purification of Monoacylglycerol with Conjugated Linoleic Acid Synthesized through a Lipase-Catalyzed Reaction by Solvent Winterization
• Effect of Vaccinium ashei reade Leaf Extracts on Lipid Metabolism in Obese OLETF Rats
• Effects of Lotus Root (the Edible Rhizome of Nelumbo nucifera) on the Deveolopment of Non-Alcoholic Fatty Liver Disease in Obese Diabetic db/db Mice
• Purification and SomeProperties of Cyclodextrinase from Bacillus coagulans
• A Novel .ALPHA.-Amino-Acid Esterase from Bacillus mycoides Capable of Forming Peptides of DD- and DL-Configurations.
• cDNA cloning and characterization of Geotrichum candidum lipase II.

もっと見る 閉じる

スポンサーリンク