Esterification of Glycosides with Glycerol ant Trimethylolpropane Moieties by Candida cylidracea Lipase(Biological Chemistry)
スポンサーリンク
概要
- 論文の詳細を見る
Glycosides, the reducing ends of which were glycerol and 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (trimethylolpropane, TMP), were esterified with oleic acid (OA) by a lipase from Candida cylindracea. Two glycosides, 1-O-β-D-galactosyl glycerol (Gal-1-Gl) and O-α-D-glucosyl TMP (Glc-TMP), were enzymatically synthesized by transglycosylation. Glc-TMP was esterified at a higher water content than Gal-1-Gl. When an equal amount of the glycosides and OA were used as substrates, almost 20% and 50% of OA were consumed for the esterification of Gal-1-Gl and Glc-TMP, respectively. Lauric, capric, and caprylic acids also gave esters. Oleic ester synthesis was compared among several related glycosides. the enzyme esterified the glycosides with a TMP moiety better than those with a glycerol moiety. The reaction was scarcely affected not only by the kind of monosaccharide moieties but also by anomeric linkage types between the moieties.
- 社団法人日本農芸化学会の論文
- 1991-08-23
著者
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Tominaga Y
Dep. Of Applied Biochemistry And Food Sci. Saga Univ.
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Yanagita Teruyoshi
Lab. Of Nutrition Biochemistry Dep. Of Applied Biochemistry And Food Sci. Saga Univ.
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KITAHATA Sumio
Osaka Municipal Technical Research Institute
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TOMINAGA Yoshio
Osaka Municipal Technical Research Institute
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NAKANO HIROFUMI
Osaka Municipal Technical Research Institute, and Yashiro Co, Ltd.,
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Yanagita Teruyoshi
Dep. Of Applied Biochemistry And Food Sci. Saga Univ.
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Tominaga Yoshio
The Organ Transplant Center Nagoya Second Red Cross Hospital
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Takenishi Shigeyuki
Osaka Municipal Technical Research lnstitute
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Nakano Hirofumi
Osaka Municipal Technical Research Institute
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Takenishi S
Osaka Municipal Technical Res. Inst. Osaka Jpn
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Takenishi Shigeyuki
Osaka Municipal Technical Research Institute
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