Chemical Transformation of Protoberberines. XII. : A Novel Synthesis of Rhoeadine Alkaloids. : An Alternative Synthesis of a Key Intermediate, Benzindenoazepine, for a Synthesis of (±)-cis-Alpinigenine and (±)-cis-Alpinine from Palmatine(Organic,Chemical)
スポンサーリンク
概要
- 論文の詳細を見る
A formal synthesis of (±)-cis-alpinigenine (3) and (±)-cis-alpinine (4) was achieved by conversion of palmatine (7) into the key intermediate, benzindenoazepine (16), via the ring D-inverted 2,3,11,12-tetraoxygenated phenolbetaine (14) and the 8,14-cycloberbine (15) through photooxygenation, photochemical valence isomerization, and regioselective C-N bond cleavage of 15 as crucial reactions.
- 公益社団法人日本薬学会の論文
- 1987-03-25
著者
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井上 満
Faculty Of Pharmaceutical Sciences Kanazawa University
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花岡 美代次
金沢大学薬学部
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花岡 美代次
Faculty Of Pharmaceutical Sciences Osaka University
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花岡 美代次
Faculty Of Pharmaceutical Sciences Kanazawa University
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安田 信吾
金沢大・薬
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安田 信吾
Faculty of Pharmaceutical Sciences, Kanazawa University
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小林 伸行
Faculty Of Pharmaceutical Sciences Kanazawa University
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