Erythro-Selective Aldol Reaction of Tricarbonyl(η^6-o-trialkylsilylbenzaldehyde)chromium(0) Complexes with Cyclic Ketene Silyl Acetals
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概要
- 論文の詳細を見る
The aldol reaction of tricarbonyl(o-trimethylsilyl(TMS)-benzaldehyde)chromium(0) complex (1a) with cyclic ketene silyl acetals (2-4) afforded the corresponding erythro products selectively. Changing the ortho TMS group to a triisopropylsilyl (TIPS) group in the complex brought about an improvement of the erythro selectivity in the case of the five-membered acetal (4).
- 社団法人日本薬学会の論文
- 1991-11-25
著者
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花岡 美代次
Faculty of Pharmaceutical Sciences, Kanazawa University
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花岡 美代次
金沢大学薬学部
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花岡 美代次
Faculty Of Pharmaceutical Sciences Osaka University
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花岡 美代次
Faculty Of Pharmaceutical Sciences Kanazawa University
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向 智里
金沢大学薬学部
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向 智里
Faculty of Pharmaceutical Sciences, Kanazawa University
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三平 亜土
Faculty of Pharmaceutical Sciences, Kanazawa University
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向 智里
Faculty Of Pharmaceutical Sciences Osaka University
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三平 亜土
Faculty Of Pharmaceutical Sciences Kanazawa University
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花岡 美代次
Institute Of Natural Medicine University Of Toyama
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