含窒素共役系の反応(第8報)Dimethyl Inidazole-4,5-dicarboxylateとAnetholeとの反応生成物の構造について
スポンサーリンク
概要
- 論文の詳細を見る
It was revealed from our previous investigation that the product obtained from the reaction of dimethyl imidazole-4,5-dicarboxylate (Ia) with anethole (II) is not a Diels-Alder type adduct (III), as proposed by Lora-Tamayo, et al., but probably a heterocyclic compound (VI). The structure of this product is assumed from the basis of its chemical behavior and spectral data. Similar treatment of Ia with butoxyethylene (IV) as in the case of II afforded dimethyl 1-(1-butoxyethyl)imidazole-4,5-dicarboxylate (V). The evidence for this structure assignment is described.
- 社団法人日本薬学会の論文
- 1973-07-25
著者
-
百瀬 雄章
大阪大学薬学部
-
富松 祥郎
Meiji College of Pharmacy
-
坂本 正徳
明治薬科大学
-
花岡 美代次
Faculty of Pharmaceutical Sciences, Kanazawa University
-
岩田 宙造
大阪大学薬学部製薬化学科
-
富松 祥郎
明治薬科大学
-
花岡 美代次
Faculty Of Pharmaceutical Sciences Osaka University
-
花岡 美代次
大阪大学薬学部
-
岩田 宙造
大阪大学薬学部
-
Sakamoto M
Meiji College Of Pharmacy
-
百瀬 雄章
Faculty Of Pharmaceutical Sciences Kanazawa University
関連論文
- Synthetic Studies on Aphidicolane and Stemodane Diterpenes. I. Synthesis of (2'R^*, 4a'S^*, 8a'R^*)-2', 8a'-Dimethyl-4a', 5', 8', 8a'-tetrahydrospiro [2,5-cyclohexadiene-1,1'(2H)-naphthalene]-3'(4'H), 4,6' (7'H)-trione
- Synthetic Studies on Spiroketal Natural Products. II. An Enantioselective Synthesis of (R)- and (S)-1,7-Dioxaspiro[5.5]undecane
- Synthetic Studies on Spiroketal Natural Products. I. : A Stereoselective Synthesis of (2R^*, 5R^*)- and (2R^*, 5S^*)-2-Methyl-1,6-dioxaspiro[4.5]decane
- 新しい入試制度を体験して
- Addition Reactions of Heterocumulenes. IV. Reactions of Diketene and Diphenylketene with N-Aryl-S, S-dimethylsulfilimines
- Studies on Antispasmodics. VI. Synthesis of N-Alkyl 6- and 7-Diarylmethyleneindolizidinium Bromides
- Studies on Antispasmodics. V. Synthesis and Anticholinergic Activity of N-Alkyl 1- and 2-Diarylmethylene-indolizidinium Bromides
- Studies on 1-Azabicyclo Compounds. XXVI. Synthesis of Ten-membered Ring Amines from 9a-Cyanomethyl-, 9a-Ethoxycarbonylmethyl-, and 1-Ethoxycarbonyl-octahydroquinolizine
- 4 Securinine及びVirosecurinineの全合成
- Total Synthesis of Securinine
- Synthesis of (±)-Methyldecamine
- 多官能性化合物2- (N-シアノイミノ) チアゾリジン誘導体の合成化学的活用
- P-18 (+)-Perhydrohistrionicotoxinの合成(ポスター発表の部)
- Addition Reactions of Heterocumulenes. III. Reaction of Diketene with Formamidine Derivatives
- 1,4-Cycloaddition Reactions of Enamine with Compounds containing the Double Bond System C=N-C=N
- Addition Reactions of Heterocumulenes. II. 1,4-Cycloaddition Reactions of Diphenylketene with Azadienes
- 1,4-Cycloaddition Reactions of Diphenylketene with Azadienes
- 含窒素共役系の反応(第4報)共役1,2-Diimine類とイソシアナート類との反応
- Erythro-Selective Aldol Reaction of Tricarbonyl(η^6-o-trialkylsilylbenzaldehyde)chromium(0) Complexes with Cyclic Ketene Silyl Acetals
- Chemical Transformation of Protoberberines. XVII. Biomimetic Introduction of an Oxy Functionality at the C-10 Position in the Benzo[c]phenanthridine Skeleton : Synthesis of 2,3,7,8,10-Pentaoxygenated Benzo[c]phenanthridine Alkaloids, Chelilutine and Sangu
- A FIRST TOTAL SYNTHESIS OF (±)-AMBININE
- Chemical Transformation of Protoberberines. XVI. Regioselective Introduction of an Oxy Functionality at the C_-Position of the Benzo[c]phenanthridine Skeleton : A Convenient Synthesis of Macarpine from Oxychelirubine
- Trimethylsilyl Trifluoromethanesulfonate-Catalyzed Aldol Reaction of Various Aldehydes with Silyl Enol Ethers
- A NOVEL DIASTEREOSELECTIVITY IN THE ALDOL REACTION OF CYCLIC KETENE SILYL ACETALS WITH COBALT-COMPLEXED AND UNCOMPLEXED PROPYNALS
- 1,6-Dihydro-3 (2H)-pyridinones. II. Synthesis of 2-Azabicyclo [2. 2. 2] octanes by the Reaction of N-Substituted 1,6-Dihydro-3 (2H)-pyridinones with 1,3-Dicarbonyl Compounds
- 1,6-Dihydro-3 (2H)-pyridinones. I. Facile Synthesis of N-Substituted 1,6-Dihydro-3 (2H)-pyridinones
- 含窒素共役系の反応(第8報)Dimethyl Inidazole-4,5-dicarboxylateとAnetholeとの反応生成物の構造について
- 含窒素共役系の反応(第7報)N-CinnamylidenemethylamineとN-Methyl-maleimideとめ付加体について
- 含窒素共役系の反応(第6報)2,3-Diphenyl-5,6-dihydropyrazineとDiethyl FumarateまたはN-Methylmaleimideとの付加体の立体構造について
- SYNTHESIS OF 3-SUBSTITUTED ISOCOUMARINS THROUGH ACYLOXYPALLADATION OF o-ALKENYLBENZOIC ACIDS
- A NOVEL SYNTHESIS OF QUINAZOLINEQUINONE AND CARBAZOLEQUINONE THROUGH ANIONIC CYCLOADDITION : ITS APPLICATION TO A SYNTHESIS OF MURRAYAQUINONE A
- Re-examination of the Synthesis of 7,8-Dimethoxy-2-methyl-3-(4', 5'-methylenedioxy-2'-vinylphenyl)iso carbostyril
- Synthesis of Pyrido[4,3-d]pyrimidin-5(6H)-ones via Anionic Cycloaddition of Methyl 2,4-Dimethoxy-6-methyl-5-pyrimidinecarboxylate with Imines
- Synthetic Studies on Anthracyclinones. XIII. Conversion of Bisanhydro-γ-rhodomycinone into Bisanhydrodaunomycinone
- 2-Oxo-1,2,3-oxathiazolidines. Its Application to Separation of Diastereoisomers of β-Amino-alcohols, 6-(4-Methoxy-2-piperidyl)-1,4-dioxaspiro [4,5] decan-6-ol and 2-Hydroxy-2-(2-piperidyl) cyclohexanone
- Synthetic Studies on Securitinine and Related Compounds. II. A Synthesis of 10a-Episecuritinine
- Synthetic Studies on Securitinine and Related Compounds. I. Stereochemistries of the Catalytic Hydrogenation Products of 6-(4-Methoxy-2-pyridyl)-1,4-dioxaspiro [4,5] decan-6-ol
- Synthetic Studies on Anthracylinones. XI. Abnormal Products from Phenolic Compounds on Methylation with Dimethyl Sulfate in Tetrahydrofuran
- Anthracyclinone類の合成研究(第10報) : Methyl 2-(1-Acetoxy-3-oxobutyl)phenylacetateの合成
- Synthesis of Bisanhydrodaunomycinone
- The Preparation of Fused Ring α, β-Unsaturated Lactones using Lithium Ethoxyacetylide. Syntheses of Dihydroactinidiolide and Actinidiolide, and Partial Synthesis of Dihydrosecurinine
- ウラジロガシ(Quercus stenophylla MAKINO)の成分研究 : 第1報 ウラジロガン葉よりFriedelinの分離
- Intramolecular Cyclization of 6-Hydroxy-6-(2-piperidyl)-2-cyclohexene-Δ^-acetic Acid γ-Lactone, a Degradation Product of Securinine
- Synthesis of Racemic Loliolide
- Structure of Securitinine.
- Convenient Synthesis of 6-(1-Acetyl-2-piperidyl)-6-hydroxy-2-cyclohexene-Δ^-acetic Acid γ-Lactone, the Key Intermediate in Total Synthesis of Securinine
- Structure of Securitinine
- Hofmann Degradations of Tetrahydrosecurinine and Tetrahydrosecurininol. Stereochemistry at C-3a of Tetrahydrosecurinine
- Synthesis and Stereochemistry in B/C Ring Juncture of Lactamcarbinol A, a Degradation Product of Securinine
- Synthetic Studies on Lythraceae Alkaloids. V. Total Synthesis of (±)-Vertaline
- Synthetic Studies on Lythraceae Alkaloids. IV. Total Synthesis of (±)-Methyldecinine
- Total Synthesis of (±)-Lagerine
- Synthetic Studies on Lythraceae Alkaloids. III. Stereoselective Total Synthesis of (±)-Decaline
- Synthetic Studies on Lythraceae Alkaloids. II. The Mannich Reaction of Isopelletierine with 3-Methoxybenzaldehyde and 3-Hydroxybenzaldehyde
- Studies on 1-Azabicyclo Compounds. XXIV. Synthesis and Stereochemistry of 10-Ethyl-, 10-Vinyl-, and 10-Ethynyl-quinolizidine Methiodides
- Studies on 1-Azabicyclo Compounds. XXII. Stereochemistry of 9a-Substituted Quinolizidine Methiodides
- Chemical Transformation of Protoberberines. XV. : A Novel and Efficient Method for the Introduction of Alkyl Groups on the C-13 Position in the Protoberberine Skeleton
- A NOVEL TOTAL SYNTHESIS OF (±)-CRYPTAUSTOLINE, A DIBENZOPYRROCOLINE ALKALOID
- A NOVEL AND BIOMIMETIC SYNTHESIS OF CHELILUTINE AND SANGUILUTINE
- A TOTAL SYNTHESIS OF (±)-CEPHALOTAXINAMIDE
- Chemical Transformation of Protoberberines. VIII. A Novel Synthesis of (±)-Fumaricine and a Formal Synthesis of (±)-Alpinigenine
- Chemical Transformation of Protoberberines. VII. Efficient Conversion of Protoberberines into Benzindenoazepines via 8,14-Cycloberbines
- Chemical Transformation of Protoberberines. V. Photochemical Valence Isomerization of Berberinephenolbetaines to 8,14-Cycloberbines, Versatile Aziridine Derivatives for a Novel and Efficient Entry to Spirobenzylisoquinolines and Benzindenoazepines
- Transformation of (±)-Ophiocarpine and (±)-13-Epiophiocarpine to (±)-α- and (±)-β-Hydrastine with Complete Retention of Configuration
- Chemical Transformation of Protoberberines. XIII. A Novel and Efficient Synthesis of Antitumor Benzo[c]phenanthridine Alkaloids, Nitidine and Fagaronine(Organic,Chemical)
- Chemical Transformation of Protoberberines. XI. A Novel Synthesis of 2,3,10,11-Tetraoxygenated Protoberberine Alkaloids from Corresponding 2,3,9,10-Tetraoxygenated Protoberberine Alkaloids(Organic,Chemical)
- SYNTHESIS OF FAGARIDINE, A PHENOLIC BENZO [c] PHENANTHRIDINE ALKALOID
- Reaction of 1-Alkyl-3,4-dihydroisoquinolines with 4-Nitrobenzoyl Cyanide and Diketene
- Reaction of N-(1-Phenylalkylidene)benzylamines with Benzoyl Cyanides
- ペリ環状反応の化学とその複素環化合物合成への応用
- Photocyclization Reactions of Epoxy Nitriles via Carbonyl Ylides. Formation of Spiroketals, Spiroethers, and a Spirolactone
- Studies on Conjugated Nitriles. VI. Reaction of 2-Methylquinoline and Related Compounds with Acyl Cyanides
- Addition Reactions of Diketene. IV. Reaction of Diketene with Thioureas, Thioamide, and Aminothiol
- 含窒素共役系の反応(第9報)Furazan誘導体とAnetholeとの環化付加反応について
- 含窒素共役系の反応(第5報) : N, N'-Bis(p-dimethylaminophenyl)ethylenediimineとp-Benzoquinoneとの反応生成物の構造について
- 含窒素共役系の反応(第3報) : 共役Schiff Baseとジフェニルケテンとの反応
- 含窒素共役系の反応(第2報) : 共役Schiff Baseとアセチレンジカルボン酸ジメチルエステルとの反応
- 含窒素共役系の反応(第1報) : 2,3-Diphenyl-5,6-dihydropyrazineとDiethyl Fumarateとの反応
- 薬学教育の現状をどう打開するか(入試制度と薬学教育)
- A New Synthesis of (±)-Agarospirol and (±)-Hinesol
- Synthetic Studies on Quadrone. I. An Approach to the Synthesis of (±)-Quadrone(Organic,Chemical)
- A NOVEL INVERSE TYPE DIELS-ALDER REACTION OF ETHYL (E)-3-(1,3-BENZOTHIAZOL-2-YL)-3-CYANOPROPENOATE AS A HIGHLY REACTIVE 1-AZA-1,3-BUTADIENE
- BENZYLIDENECYANOMETHYL-1,3-BENZAZOLES AS 1-AZA-1,3-BUTADIENES
- Excellent Chiral Induction by Diene Iron-Tricarbonyl Moiety. I : Diastereoselective [4+2] Type Cycloaddition of 1-Azatriene Iron-Tricarbonyl Complex
- A Modified Procedure for the Synthesis of Spirodienones from Phenolic α-Diazoketones
- Synthetic Studies on Quadrone. II. Synthesis of Methyl (1R^*,3aR^*,6aR^*)-2,2-Dimethyl-2,3,3a,4,6,6a-hexahydro-1-(2-hydroxyethyl)-4-methylene-5-oxo-3a(1H)-pentaleneacetate, a Key Intermediate for the Synthesis of (±)-Quadrone(Organic,Chemical)
- Neighboring Hydroxyl Group Participation in Metal-Ammonia Reduction of Spirocyclic Dienones
- Total Synthesis of (±)-α-Chamigrene and Brominated Chamigrene
- 38 スピロベチバン類の合成研究
- An Approach to the Stereoselective Synthesis of Nidifocene. II.Total Synthesis of (±)-Dehalogenonidefocene
- 43(PA1-1) カミグラン型セスキテルペン類の合成研究(ポスター発表の部)
- Photochemical Oxidation. II. Biogenetic-Type Conversion of Ligularol and Furanoeremophilane into 6β-Hydroxyeremophilenolide and Eremophilenolide
- An Approach to the Stereoselective Synthesis of Nidifocene. III.Total Syntheses of the Stereoisomers of (±)-Nidifocene from(±)-Dehalogenonidifocene
- 11 ハロカミグラン型セスキテルペン類縁体の合成研究(ポスター発表の部)
- An Approach to the Stereoselective Synthesis of Nidifocene : Regio- and Stereoselective Synthesis of vic-trans-Bromochlorocyclohexane Ring System
- Synthesis of Four Possible Isomers of 9-(Bromomethylene)-1,2,5-trimethylspiro[5.5]undeca-1,7-dien-3-one : Structure Elucidation of a Brominated Rearranged Chamigrane-Type Sesquiterpene
- 第7回薬物の分子設計と新薬開発に関する韓日合同シンポジウム
- 大学側と受入側との意見交換の場として必要(薬学会年会に教育部会を置くことの是非)
- 6年制に向けた教育体制の充実--薬学教育の現状を考える (特集 薬学教育の転換期)
- 2-Acetyl-1-naphthoic and 2-Acetyl-3,4-dihydro-1-naphthoic Acid.