Uber eine neue Nitrierung des Chinolin-1-oxydes. (3).

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概要

• 論文の詳細を見る

• Die Nitrierung von Chinolin-1-oxyd mittels Benzoylnitrat wurde in der Weise verbessert und vereinfacht, dass man auf Chinolin-1-oxyd in Chloroform-Losung zuerst Benzoylchlorid und dann Silbernitrat einwirken lasst. Beim analogen Behandeln von Chinolin-1-oxyd mit Acetylchlorid und Silbernitrat konnte man ausser dem 3-und 3,6-Dinitroderivat eine kleine Menge 6-Nitrochinolin-1-oxyd aber kein 1-Acetoxy-3,6-dinitrocarbostyril isolieren. Das letztere konnte man jedoch beim Einwirken der uberschussigen Reagenzien auf 3-Nitrochinolin-1-oxyd erhalten. 3,6-Dinitrochinolin-1-oxyd ergab bei der Einwirkung von Benzoylnitrat 1-Benzoyloxy-3,6-dinitrocarbostyril. Ein umgestalteter Mechanismus fur die Reaktion wurde vorgeschlagen.

• 公益社団法人日本薬学会の論文
• 1959-05-10

著者

• 金子 主税

  Faculty Of Pharmaceutical Sciences Kanazawa University

• 金子 主税

  Pharmaceutical Institute Medical Faculty University Of Tokyo

• 落合 英二

  Pharmazeutische Fakultat, Universitat Tokio

• 落合 英二

  ITSUU Laboratory

• 落合 英二

  Pharm. Institut D. Mediz. Fakultat D. Universitat Tokyo

• 落合 英二

  Faculty Of Pharmaceutical Sciences University Of Tokyo And Research Laboratory Shionogi & Co. Lt

• 金子 主税

  Pharmaceutical Institute Tohoku University

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