SELECTIVE PROTECTION OF THE PRIMARY HYDROXYL GROUPS OF OXETANOCIN A AND CONFORMATIONAL ANALYSIS OF O-PROTECTED OXETANOCIN A
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概要
- 論文の詳細を見る
One of the two primary hydroxyl groups of oxetanocin A was protected selectively with acetyl and o-nitrobenzyl groups using enzymatic and photochemical reactions, respectively. On the basis of ^1H-NMR spectroscopy and NOE experiment, 4'-O-protected oxetanocin A was found to take syn conformation in an aprotic solvent irrespective of the kind of protecting group owing to an intramolecular hydrogen bond.
- 公益社団法人日本薬学会の論文
- 1995-05-15
著者
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金子 主税
東北大学
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金子 主税
Pharmaceutical Institute Medical Faculty University Of Tokyo
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片桐 信弥
Pharmaceutical Institute, Tohoku University
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片桐 信弥
Health Sci. Univ. Hokkaido Hokkaido Jpn
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片桐 信弥
Pharmaceutical Institute Tohoku University
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牧野 真士
Pharmaceutical Institute, Tohoku University
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Katagiri N
Pharmaceutical Institute Tohoku University
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牧野 真士
Pharmaceutical Institute Tohoku University
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