Uber 2-Hydroxychinolin-1-oxyd.
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概要
- 論文の詳細を見る
Bei der Chlorierung von 2-Hydroxychinolin-1-oxyd mit Phosphoroxychlorid wurde 2,4-Dichlorchinolin erhalten. 2-Hydroxychinolin-1-oxyd ergab beim Nitrieren mit Salpetersaure in Eisessig-Losung das 6,8-Dinitroderivat. Das Acetyl-, Benzoyl-und Tosylderivate von 2-Hydroxychinolin-1-oxyd und seiner 6,8-und 3,6-Dinitroderivate wurden hergestellt. Ihre Konstitutionen wurden durch die IR-spektrographische Untersuchung als die 1-Acyloxycarbostyril-Derivate festgestellt. 1-Benzoyloxycarbostyril widersteht der Einwirkung von Benzoylnitrat, wahrend Carbostyril dabei 6-Nitroderivat ergibt. Die katalytische Reduktion des Tosylates von 2-Hydroxychinolin-1-oxyd mit Palladium-Kohle in Athanol-Losung ergab 3,4-Dihydrocarbostyril.
- 公益社団法人日本薬学会の論文
- 1959-05-10
著者
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金子 主税
Faculty Of Pharmaceutical Sciences Kanazawa University
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金子 主税
Pharmaceutical Institute Medical Faculty University Of Tokyo
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金子 主税
Pharmaceutical Institute Tohoku University
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