A NOVEL PHOTOCHEMICAL PRENYLATION REACTION OF HETEROAROMATICS INVOLVING AN ENONE FUNCTION IN THEIR RING SYSTEM

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概要

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• In a novel photochemical prenylation of heteroaromatics involving an enone function in their ring system, the key step is an acid-catalyzed C-C bond fission in the head-to-tail adduct formed by photocycloaddition of these heteroaromatics to 2-methyl-3-buten-2-ol to give the heteroaromatics having a 3-methylbut-2-enyl function (or its equivalent) at the α-position of the enone system. Examples using 2-quinolones, 2-pyridones, and coumarins are reported.

• 公益社団法人日本薬学会の論文
• 1982-04-25

著者

• 金子 主税

  Faculty Of Pharmaceutical Sciences Kanazawa University

• 百瀬 祐

  Faculty of Pharmaceutical Sciences, Kanazawa University

• 内藤 俊彦

  Faculty of Pharmaceutical Sciences, Kanazawa University

• 百瀬 祐

  Faculty Of Pharmaceutical Sciences Kanazawa University

• 金子 主税

  Pharmaceutical Institute Tohoku University

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