Uber eine neue Nitrierung des Chinolin-N-oxydes. (2).

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概要

• 論文の詳細を見る

• Bei der Nitrierung von Chinolin-N-oxyd mit uberschussigem Benzoylnitrat in Chloroform-Losung entsteht ausser 3-Nitrochinolin-N-oxyd eine nadelformige schwachgelbe Substanz vom Schmp. 258° (u. Zers.) als das Hauptprodukt, dessen Konstitution als N-Benzoyloxy-3,6-dinitrocarbostyril festgestellt wurde. Das letztere entsteht auch bei analoger Nitrierung von 3- bzw. 6-Nitrochinolin-N-oxyd mit Benzoylnitrat. 5-bzw. 7-Nitrochinolin-N-oxyd ergab bei ganz analoger Nitrierung mit Benzoylnitrat je ein isomeres Produkt von der Zusammensetzung C_<16>H_9O_7N_3,dessen Konstitution hochstwahrscheinlich 3,5- bzw. 3,7-Dinitro-N-benzoyloxycarbostyril ist.

• 公益社団法人日本薬学会の論文
• 1959-03-20

著者

• 金子 主税

  Faculty Of Pharmaceutical Sciences Kanazawa University

• 金子 主税

  Pharmaceutical Institute Medical Faculty University Of Tokyo

• 落合 英二

  Pharmazeutische Fakultat, Universitat Tokio

• 落合 英二

  ITSUU Laboratory

• 落合 英二

  Pharm. Institut D. Mediz. Fakultat D. Universitat Tokyo

• 落合 英二

  Faculty Of Pharmaceutical Sciences University Of Tokyo And Research Laboratory Shionogi & Co. Lt

• 金子 主税

  Pharmaceutical Institute Tohoku University

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