炭素-炭素二重結合(特にエノン類)への分子フッ素の付加反応

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概要

• 論文の詳細を見る

• Some recent topics concerning the addition of molecular fluorine to C=C bonds are discussed together with the mechanistic clarification of the syn-addition and the formation of the rearrangement products. The entire scheme for the addition reaction is the formation of a perpendicular π-complex at the initial stage, which leads to a tight ion pair as the transition state. The tight ion pair then either collapses directly to the syn-addition product, or affords indirectly the carbocation rearrangement product. It is postulated that the direct precursor of the rearrangement products is not a free carbocation but a loose ion pair which is formed from the tight ion pair.

• 公益社団法人日本薬学会の論文
• 1994-03-25

著者

• 千葉 淳

  Pharmaceutical Institute Tohoku University

• 金子 主税

  東北大学

• 金子 主税

  東北大学薬学部

• 豊田 朱見

  東北大学薬学部

• 千葉 淳

  東北大学薬学部

• 豊田 朱見

  東北大学薬学部薬化学教室

• Chiba J

  Institute For Materials Research Tohoku University

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