Studies on the Syntheses of Heterocyclic Compounds. CDLXXXIII. Synthesis of Homoaporphine and Attempts to Synthesize C-Noraporphine by Pschorr Reaction
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概要
- 論文の詳細を見る
Photolysis of the diazonium salt derived from 1-(2-amino-4-hydroxy-5-methoxy-phenethyl)-7-hydroxy-1,2,3,4-tetrahydro-6-methoxy-2-methylisoquinoline (V) gave, 1,11-dihydroxy-2,10-dimethoxyhomoaporphine (IX), which was identical with the rearranged product of kreysiginone (VII) by acid. The same reaction of 1-(2-aminophenyl)-1,2,3,4-tetrahydro-6,7-dimethoxy-2-methylisoquinoline (XXI) gave an abnormal product, 3,4-dihydro-6,7-dimethoxy-1-phenylisoquinoline (XXV), in addition to the deamination product (XXII) and the phenolic isoquinoline (XXIII).
- 公益社団法人日本薬学会の論文
- 1972-07-25
著者
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福本 圭一郎
東北大・薬
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福本 圭一郎
Pharmaceutical Institute Tohoku University School Of Medicine
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渋谷 皓
東北大学薬学部
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SUBRAMANIANI P.S.
Department of Chemistry, Presidency College
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Subramaniani P.s.
Department Of Chemistry Presidency College
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中野 卓雄
Pharmaceutical Institute Tohoku University
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清野 ちづ子
Pharmaceutical Institute Tohoku University
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