Cularine and Related Compounds. IV. The Oximination and Reduction of 2,3,6-Trimethoxydibenzo [b, f] oxepin-10 (11H) -one.
スポンサーリンク
概要
- 論文の詳細を見る
Oximination of 2,3,6-trimethoxydibenzo [b, f] oxepin-10 (11H)-one (II) yielded three compounds, among which mono- and di-oximes were elucidated. Catalytic hydrogenation of the ketone (II) in the presence of Adams catalyst in acetic acid gave the carbinol (VII), m. p. 167°, accompanied by a small amount of the starting material. When the carbinol (VII) was heated with p-toluenesulfonic acid at 120〜140° for 10 minutes, VII was dehydrated and yielded yellow needles (VIII), m. p. 115〜116.5°.
- 1963-10-25
著者
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福本 圭一郎
東北大・薬
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亀谷 哲治
Pharmaceutical Institute Medical Faculty University Of Osaka
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福本 圭一郎
Pharmaceutical Institute Tohoku University School Of Medicine
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