Reactions of β-Carbonylethylthiosulfates and β-Carbamoylethyl Disulfides with Amines
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概要
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The reactions of sodium 2-phenylcarbamoylethylthiosulfate, sodium 2-cyclohexyl-carbamoylethylthiosulfate and sodium 2-benzoylethylthiosulfate with aqueous alkylamines were attempted and found to give the corresponding N-β-carbonylethyl-N-alkylamines and sometimes bis (β-carbonylethyl) sulfides, though the same reactions in anhydrous state is known to give the corresponding disulfides as the only product isolated. The reaction between bis (2-phenylcarbamoylethyl) disulfide or bis (2-cyclohexylcarbamoylethyl) disulfide and aqueous cyclohexylamine was also attempted under similar conditions and found to give the corresponding sulfides. The mechanisms of these reactions were also discussed.
- 公益社団法人日本薬学会の論文
- 1973-04-25
著者
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古川 潮
Faculty Of Pharmaceutical Sciences Kumamoto University
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林 清五郎
Faculty Of Pharmaceutical Sciences Kumamoto University
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小島 洋子
Faculty Of Pharmaceutical Sciences Kumamoto University
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幸 健
Faculty of Pharmaceutical Sciences, Kumamoto University
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清藤 らん子
Faculty of Pharmaceutical Sciences, Kumamoto University
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幸 健
Faculty Of Pharmaceutical Sciences Kumamoto University
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林清 五郎
Faculty Of Pharmaceutical Sciences Kumamoto University
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清藤 らん子
Faculty Of Pharmaceutical Sciences Kumamoto University
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