Determination of the Absolute Configuration of (-)-2-Bromosuccinamic Acid by X-Ray Diffraction Method
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概要
- 論文の詳細を見る
Crystals of (-)-2-bromosuccinamic acid (C_4H_6O_3NBr) are orthorhombic, with space group P2_12_12_1 and lattice parameters a=7.70,b=9.23,c=8.88 A, containing four molecules in the unit cell. The structure was solved by the heavy atom method coupled with three-dimensional Fourier and difference Fourier synthese. The refinement was carried out by the full-matrix least-squares calculations. The final (R) value was 0.15. The absolute configuration was established to be (S) (-) by the anomalous dispersion method. The molecular and crystal structure were also discussed.
- 公益社団法人日本薬学会の論文
- 1969-12-25
著者
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村上 泰興
Faculty of Pharmaceutical Sciences, University of Tokyo
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飯高 洋一
Faculty of Pharmaceutical Sciences, The University of Tokyo
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村上 泰興
School Of Pharmaceutical Science Toho University
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飯高 洋一
Faculty Of Pharmaceutical Sciences The University Of Tokyo
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