Palladium (II) Chelates of 1,1-Dimethyl-3-(4-methyl-2-thiazolyl) thiourea and Related Thioureas

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概要

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• Pd (II) chelates of 1,1-dimethyl-3-(4-methyl-2-thiazolyl) thiourea and related N-(2-thiazolyl)-thioureas were prepared and their molecular structures were determined by means of spectroscopic, thermochemical, and X-ray crystallographic measurements, in order to establish the identity of the colored substances in the spectrophotometric determination of Pd (II) with the thiazolyl-thioureas. The results indicated that Pd (II) formed 1 : 2 chelates with the thiazolylthioureas and that the ligands were bidentate and coordinated through the thiourea sulfur and thiazole nitrogen atoms. The geometry of Pd (II) coordination was roughly square-planar and the configuration of the two thiazolylthiourea molecules was cis.

• 社団法人日本薬学会の論文
• 1985-11-25

著者

• 松島 美一

  共立薬科大学

• 飯高 洋一

  Faculty of Pharmaceutical Sciences, The University of Tokyo

• 与田 玲子

  共立薬科大学

• 与田 玲子

  Kyoritsu College of Pharmacy

• 松島 美一

  Kyoritsu College of Pharmacy

• 藤江 忠雄

  Kyoritsu College of Pharmacy

• 飯高 洋一

  School Of Medicine Teikyo University

• 山本 有一

  Kyoritsu College of Pharmacy

• 飯高 洋一

  Faculty Of Pharmaceutical Sciences The University Of Tokyo

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