Novel Sesquiterpenes from Alpinia intermedia GAGNEP.(Pharmacognosy,Chemical)

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概要

• 論文の詳細を見る

• Three novel sesquiterpene peroxides, hanalpinol peroxide (I), isohanalpinol (II), and aokumanol (III), a new secoguaiane-type sesquiterpene, epialpinolide (IV), and a new elemophilane-type sesquiterpene, Δ^<11(12)-eremophilen-10β-ol (V), have been isolated from the rhizomes of Alpinia intermedia together with eight known sesquiterpenes, hanalpinol (VI), hanalpinone (VII), isohanalpinone (VIII), alpinenone (IX), furopelargone B (X), furopelargone A (XI), intermedeol (XII) and β-selinene (XIII). The structures of I-V were determined by spectroscopic methods, chemical conversion, and X-ray analysis. Their biosynthetic relationships are discussed. From the point of view of chemotaxonomy, it is suggested that Alpinia intermedia and Alpinia japonica are closely related plants.

• 公益社団法人日本薬学会の論文
• 1987-07-25

著者

• 飯高 洋一

  Faculty of Pharmaceutical Sciences, The University of Tokyo

• 糸川 秀治

  Tokyo College Of Pharmacy

• 糸川 秀治

  東京薬科大学 薬学部

• 森田 博史

  Tokyo College of Pharmacy

• 飯高 洋一

  西東京大・理工

• 渡辺 謹三

  Tokyo College of Pharmacy

• 小林 剛

  Tokyo College of Pharmacy

• 飯高 洋一

  Faculty Of Pharmaceutical Sciences The University Of Tokyo

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