Oxidative Decarboxylation of Arylacetic Acids with Manganese(III)Acetate
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概要
- 論文の詳細を見る
The oxidative decarboxylation reactions of arylacetic acids to arylcarbinols were compared for Mn(III) acetate, Ce(IV) ammonium nitrate and a combination reagent of Co(III) acetate-Cu(II) acetate. The reaction with Mn(III)acetate in acetic acid gave the corresponding arylcarbinyl acetate usually in good yield. The reaction was particularly easy when the substrate carried an electron-donating group at the para position of the aromatic ring, or when the acid was secondary or tertiary. In contrast, the product generated with the other reagents was either a mixture containing over-oxidation products or products formed via a different route.
- 公益社団法人日本薬学会の論文
- 1996-12-15
著者
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毛利 邦彦
Showa College Of Pharmaceutical Sciences
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TSUDA YOSHISUKE
Faculty of Pharmaceutical Sciences, Kanazawa University
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ISOBE Kimiaki
Showa College of Pharmaceutical Sciences
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MOHRI Kunihiko
Showa Pharmaceutical University
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Mohri K
Showa College Of Pharmaceutical Sciences
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Isobe K
Showa College Of Pharmaceutical Sciences
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Isobe Kimiaki
Showa Pharmaceutical University
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Tsuda Yoshisuke
Faculty Of Pharmaceutical Sciences Kanazawa University
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MAMIYA Junko
Showa College of Pharmaceutical Sciences
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KASAHARA Yuka
Showa College of Pharmaceutical Sciences
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Tsuda Y
Faculty Of Pharmaceutical Sciences And High Technology Research Center Kobe Gakuin University
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Mamiya Junko
Showa College Of Pharmaceutical Sciences:kanazawa University
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Kasahara Yuka
Showa College Of Pharmaceutical Sciences:kanazawa University
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