Acacia concinna Saponins. II. Structures of Monoterpenoid Glycosides in the Alkaline Hydrolysate of the Saponin Fraction
スポンサーリンク
概要
- 論文の詳細を見る
From the AcOEt-soluble fraction of the alkaline hydrolyzate of the highly polar saponin fraction of pods of Acacia concinna, two monoterpenes, (2E)-2,6-dimethyl-6-hydroxy-2,7-octadienoic acid (menthiafolic acid, 1) and (2E)-6-hydroxy-2-hydroxymethyl-6-methyl-2,7-octadienoic acid (4), and their glycosides, (6R)- and (6S)-menthiafolic acid-6-O-β-D-quinovoside (2a and 2b) and (6R)- and (6S)-menthiafolic acid-6-O-β-D-xyloside (3a and 3b), were isolated. A more polar fraction gave, after methylation with diazomethane, (6R)- and (6S)-(2E)-6-hydroxy-2-hydroxymethyl-6-methyl-2,7-octadienoic acid-6-O-β-D-quinovoside as their methyl esters (5a and 5b). Compounds 2a, 3a, 4,5a, and 5b are new. The structures of the above compounds were determined mainly by the application of spectroscopic methods.
- 公益社団法人日本薬学会の論文
- 1997-05-15
著者
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Kiuchi Fumiyuki
Faculty of Pharmacy, Keio University
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Obata Tohru
Department Of Experimental Therapeutics Cancer Research Institute Kanazawa University
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TSUDA YOSHISUKE
Faculty of Pharmaceutical Sciences, Kanazawa University
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Kiuchi F
Graduate School Of Pharmaceutical Sciences Kyoto University
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Kikuchi F
Faculty Of Pharmaceutical Sciences Kanazawa University:(present Address)graduate School Of Pharmaceu
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Kikuchi F
Faculty Of Pharmaceutical Sciences Kanazawa University
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Kiuchi Fumiyuki
Faculty Of Pharmaceutical Sciences Kanazawa University
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GAFUR Md.Abdul
Faculty of Pharmaceutical Sciences, Kanazawa University
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OBATA Tohoru
Faculty of Pharmaceutical Sciences, Kanazawa University
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TACHIBANA Akiko
Faculty of Pharmaceutical Sciences, Kanazawa University
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Gafur Mohammod
Faculty Of Pharmaceutical Sciences Kanazawa University
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Kiuchi Fumiyuki
Graduate School Of Pharmaceutical Sciences Kyoto University
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Kiuchi F
Kanazawa Univ. Kanazawa Jpn
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Obara Takumi
Department Of Experimental Therapeutics Cancer Research Institute Kanazawa University
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Obata Takaaki
Department Of Experimental Therapeutics Cancer Research Institute Kanazawa University
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Tsuda Yoshisuke
Faculty Of Pharmaceutical Sciences Kanazawa University
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Tsuda Y
Faculty Of Pharmaceutical Sciences And High Technology Research Center Kobe Gakuin University
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Tachibana Akiko
Faculty Of Pharmaceutical Sciences Kanazawa University
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