Chemistry of Oxo-Sugars. IV. Isomerization of 4-Oxoglycosides in a Pyridine Solution
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概要
- 論文の詳細を見る
4-Oxoglycosides of xylo-configuration (1a, 1b) rearranged in pyridine-d_5 to give exclusively 3-oxoglycosides of ribo-configuration through enediol intermediates. On the other hand, 4-oxoglycosides of lyxo- and arabino-configuration (5,6) gave an epimeric mixture of both isomers. The reason for this difference was discussed on the basis of AM1 calculations.
- 公益社団法人日本薬学会の論文
- 1996-01-15
著者
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TSUDA YOSHISUKE
Faculty of Pharmaceutical Sciences, Kanazawa University
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Liu Hong-min
(present Address)department Of Chemistry Zhengzhou University
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Tsuda Yoshisuke
Faculty Of Pharmaceutical Sciences Kanazawa University
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