STEREOSELECTIVE SYNTHESIS OF AN ALKENOID-TYPE ERYTHRINAN ALKALOID, (±)-ERYTHRATIDINE
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概要
- 論文の詳細を見る
Oxidation of (±)-demethylerysotramidine (2) with mCPBA gave the α-1,2-epoxide (3) as a single product, which was methylated to 4,then treated with SmI_2 in THF-MeOH to give 8-oxoerythratidine (5) in good yield. Finally, 5 was reduced with a LiAlGH_4-AlCl_3 combination to the natural alkaloid, (±)-erythratidine (1).
- 公益社団法人日本薬学会の論文
- 1996-12-15
著者
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TSUDA YOSHISUKE
Faculty of Pharmaceutical Sciences, Kanazawa University
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HOSOI Shinzo
Faculty of Pharmaceutical Sciences, Kanazawa University
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Hosoi Shinzo
Faculty Of Pharmaceutical Sciences Kanazawa University
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Tsuda Yoshisuke
Faculty Of Pharmaceutical Sciences Kanazawa University
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SATO Masakazu
Faculty of Pharmaceutical Sciences, Kanazawa University
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NAGAO Motoyoshi
Faculty of Pharmaceutical Sciences, Kanazawa University
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Sato Masakazu
Faculty Of Pharmaceutical Sciences Kanazawa University
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Nagao M
Faculty Of Pharmaceutical Sciences Kanazawa University
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