Dioxopyrrolines.LXII. Diels-Alder Reaction of 1-Aryl-4-and 5-methoxycarbonyl-1H-pyrrole-2,3-diones with Various 1,3-Dienes

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概要

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• Two new dioxopyrrolines (1-aryl-4-methoxycarbonyl-1H-pyrrole-2,3-dione 6 and the 5-methoxycarbonyl isomer 8) behaved as good dienophiles to some kind of 1,3-dienes examined. In most cases, the products were explained by the reaction where the largest lobe of HOMO of dienes reacted to the larger LUMO of dienophiles in an expected cis-endo manner. However, in the reactions of 8 with alkylbutadienes, piperylene and isoprene, abnormality in the reaction was observed, which was well explained by taking account of steric factors.

• 公益社団法人日本薬学会の論文
• 2003-05-01

著者

• 毛利 邦彦

  Showa College Of Pharmaceutical Sciences

• Yokoyama Kazumasa

  Central Research Laboratories Green Cross Corporation Ltd.

• Yokoi T

  Faculty Of Pharmaceutical Sciences Kobe Gakuin University

• Tsuda Yuko

  Faculty Of Pharmaceutical Sciences Kobe Gakuin University:cooperative Research Center Of Life Scienc

• Tsuda Y

  Faculty Of Pharmaceutical Sciences Kobe Gakuin University

• Tsuda Yuko

  Faculty Of Pharmaceutical Science Kobe Gakuin University

• ISOBE Kimiaki

  Showa College of Pharmaceutical Sciences

• Yoshida Yuki

  Showa Pharmaceutical University

• Yokoyama K

  Showa Pharmaceutical University

• MOHRI Kunihiko

  Showa Pharmaceutical University

• YOKOYAMA Katsumi

  Showa Pharmaceutical University

• KOMIYA Hiroaki

  Showa pharmaceutical University

• WATANABE Yuhya

  Showa Pharmaceutical University

• TSUDA Yosisuke

  H. E. J. Research Instiute of Chemistry. University of Karachi

• Mohri K

  Showa College Of Pharmaceutical Sciences

• Isobe K

  Showa College Of Pharmaceutical Sciences

• Isobe Kimiaki

  Showa Pharmaceutical University

• Yoshida Y

  Yakult Central Inst. For Microbiological Res.

• Yamanouchi K

  Faculty Of Pharmaceutical Sciences The University Of Tokushima

• Tsuda Y

  Faculty Of Pharmaceutical Sciences And High Technology Research Center Kobe Gakuin University

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