Interaction between Trehalose and Alkaline-Earth Metal Ions
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概要
- 論文の詳細を見る
We investigated the interaction between trehalose and alkaline-earth metal ions. The nuclear relaxation times of carbon atoms of trehalose were shortened by addition of the alkaline-earth chloride salts, MgCl2, CaCl2, and SrCl2, indicating that trehalose formed metal-complexes with the alkaline-earth metal chlorides. From the data of the 1H–1H coupling constants of trehalose in the presence of the alkaline-earth chlorides, it appeared that trehalose formed complexes with MgCl2, and CaCl2 at the various complexing sites: Mg2+ was coordinated to O-4 and O-4′ of trehalose, and Ca2+ to O-2 and O-3. We succeeded in the preparation of two types of crystals of the trehalose/CaCl2. One was a crystal consisting of trehalose, CaCl2, and water in a ratio of 1:1:1. The other was an anhydrous crystal containing trehalose and CaCl2 in a ratio of 1:2. Several applications of the complexing between trehalose and the metal ions for food processing are proposed.
- 社団法人 日本農芸化学会の論文
- 2005-01-23
著者
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Sakurai Minoru
Center of Biological resources and Informatics, Tokyo Institute of Technology
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Kurimoto Masashi
Amase Institute, Hayashibara Biochemical Laboratories Inc.
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FUKUDA Shigeharu
Amase Institute, Hayashibara Biochemical Laboratories, Inc.
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Fukuda S
Biomedical Inst. Res. Center Hayashibara Biochemical Laboratories Inc.
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Fukuda Shigeharu
Glycoscience Institute Hayashibara Biochemical Laboratories Inc.
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Kohguchi Michihiro
Fujisaki Institute Hayashibara Biochemical Laboratories Inc.
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Kurimoto M
Amase Institute Hayashibara Biochemical Laboratories Inc.
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Kibata Masayoshi
Hayashibara Biochemical Laboratories Inc.
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Oku Kazuyuki
Glycoscience Institute Research Center Hayashibara Biochemical Laboratories Inc.
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Oku Kazuyuki
Amase Institute Hayasibara Biochemical Laboratories Inc.
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Kubota Michio
Amase Institute, Hayashibara Biochemical Laboratories, Inc.
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Sakurai Minoru
Center For Biol. Res. Info. .tokyo Inst. Tech
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Taniguchi Yoshifumi
Biomedical Institute, Research Center, Hayashibara Biochemical Laboratories, Inc.
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Kubota Michio
Glycoscience Institute Research Center Hayashibara Biochemical Laboratories Inc.
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Kurose Mayumi
Glycoscience Institute Research Center Hayashibara Biochemical Laboratories Inc.
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Mukai Kazuhisa
Glycoscience Institute Research Center Hayashibara Biochemical Laboratories Inc.
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KUROSE Mayumi
Amase Institute, Hayashibara Biochemical Laboratories, Inc.
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Kubota M
Hayashibara Biochemical Laboratories Inc.
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Fukuda Shigeharu
Fujisaki Institute Hayashibara Biochemical Laboratories Inc.
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TUJISAKA Yoshio
Amase Institute, Hayashibara Biochemical Laboratories, Inc.
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Kubota M
Division Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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Tsujisaka Y
Biomedical Institute Research Center Hayashibara Biochemical Laboratories Inc.
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Kurimoto M
Fujisaki Institute Hayashibam Biochemical Laboratories Inc.
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Maruta K
Glycoscience Institute Research Center Hayashibara Biochemical Laboratories Inc.
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Taniguchi Yoshifumi
Biomedical Institute Research Center Hayashibara Biochemical Laboratories Inc.
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Sakurai Minoru
Center For Biol Res Info Tokyo Inst. Tech
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Fukuda Shigeharu
Glycoscience Institute, Research Center, Hayashibara Biochemical Laboratories, Inc.
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