Novel Metabolite of Trichloroethylene in a Methanotrophic Bacterium, Methylocystis sp. M, and Hypothetical Degradation Pathway
スポンサーリンク
概要
- 論文の詳細を見る
Previously, a new type II methanotrophic bacterium, Methylocystis sp. M (strain M), was isolated in our laboratory [H. Uchiyama et al., Agric. Biol. Chem., 53,2903-2907 (1989)]. In this paper, metabolites resulting from the degradation of trichloroethylene (TCE) by strain M were studied with gas chromatography-mass spectrometry. Ttichloroacetic acid, dichloroacetic acid, and a small amount of 2,2,2-trichloroethanol were detected in the water-soluble fraction of the reaction mixture. These results suggest that the conversion of TCE to trichloroacetaldehyde via a Cl-shift reaction, followed by the formation of trichloroacetic acid and 2,2,2-trichloroethanol, as well as a spontaneous breakdown of TCE oxide, with subsequent formation of dichloroacetic acid, etc., is involved in the TCE degradation pathway of the methanotrophic bacterium.
- 社団法人日本農芸化学会の論文
- 1992-03-23
著者
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Nakajima Toshiaki
Institute Of Applied Biochemistry University Of Tsukuba
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NAKAJIMA Terumi
Suntory Institute for Bioorganic Research
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Uchiyama H
National Inst. Environmental Studies Ibaraki Jpn
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Uchiyama Hiroo
National Institute Of Environmental Studies
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Uchiyama Hiroo
National Institute For Environmental Studies
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Uchiyama Hiroo
Water And Soil Environment Division National Institute For Enviromental Studies
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YAGI OSAMI
National Institute of Environmental Studies
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Nakajima T
Suntory Institute For Bioorganic Research
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Nakahara T
Institute Of Applied Biochemistry University Of Tsukuba:(present Address)ryutsu Keizai University
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Yagi Osami
Water And Soil Environmental Studies
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Yagi Osami
National Institute For Environmental Studies
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NAKAHARA Tadaatu
Institute of Applied Biochemistry, University of Tsukuba
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Nakahara Tadaatu
Institute Of Applied Biochemistry University Of Tsukuba
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Yagi O
Univ. Tokyo Tokyo Jpn
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